10-溴-1,2,3,4,5,6,7,8,13,13,14,14-十二氯-1,4,4a,4b,5,8,8a,12b-八氢-1,4:5,8-二甲桥三亚苯基合成路线 （共 3 条）
80789-65-710-溴-1,2,3,4,5,6,7,8,13,13,14,14-十二氯-1,4,4a,4b,5,8,8a,12b-八氢-1,4:5,8-二甲桥三亚苯基
→
反应条件
1: 74 percent / Fe powder, Br2 / various solvent(s) / 2 h / Heating 2: 63 percent 3: 52 percent / PhLi / tetrahydrofuran; cyclohexane / 1 h / 25 °C 4: 85 percent / m-CPBA / acetonitrile / 2 h / Heating View Scheme
参考文献
LeHoullier, Craig S.; Gribble, Gordon W.
Journal of Organic Chemistry, 1983 , vol. 48, # 14 p. 2364 - 2366
80789-65-710-溴-1,2,3,4,5,6,7,8,13,13,14,14-十二氯-1,4,4a,4b,5,8,8a,12b-八氢-1,4:5,8-二甲桥三亚苯基
→
反应条件
1: 74 percent / Fe powder, Br2 / various solvent(s) / 2 h / Heating 2: 63 percent View Scheme
参考文献
LeHoullier, Craig S.; Gribble, Gordon W.
Journal of Organic Chemistry, 1983 , vol. 48, # 14 p. 2364 - 2366
80789-65-710-溴-1,2,3,4,5,6,7,8,13,13,14,14-十二氯-1,4,4a,4b,5,8,8a,12b-八氢-1,4:5,8-二甲桥三亚苯基
→
84605-00-510-溴-1,2,3,4,5,6,7,8,13,13,14,14-十二氯-1,4,4a,4b,5,8,8a,12b-八氢-11-硝基-1,4-5,8-二甲桥三亚苯
反应条件
sulfuric acid; nitric acid in sulfuryl dichloride
参考文献
Fenyes,J.G.E.
Journal of Organic Chemistry, 1962 , vol. 27, p. 2614 - 2618
