1: (ethoxycarbonylmethyl)-triphenylphosphonium bromide With sodium hydroxide in dichloromethane; water
T=2°C; 0.5 h;
2: 1.3-dihydroxypropan-2-one in dichloromethane; water
T=20°C; 22 h; Product distribution / selectivity;
Rh6(CO)12; water; triethylamine in 1,4-dioxane
T=80°C; P=76000 Torr; 5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
Rh6(CO)12; water; triethylamine in 1,4-dioxane
T=80°C; P=76000 Torr; 5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
