(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
potassium hexamethylsilazane in toluene 7 h;
参考文献
UNIVERSITY OF SOUTHERN CALIFORNIA; Prakash, G.K. Surya; Jog, Parag V.; Batamack, Patrice T.D.; Olah, George A.
Patent: US2014/66640 A1, 2014 ;
Location in patent: Paragraph 0057 ;
反应条件
tetrakis(dimethylamino)ethylene in benzonitrile T=20°C; 1 h;
参考文献
Pawelke, G.
Journal of Fluorine Chemistry, 1989 , vol. 42, p. 429 - 434
反应条件
tris(diethylamino)phosphine oxide in benzonitrile 1) -60 deg C, 1 h, 2) rt, overnight;
参考文献
Krishnamurti, Ramesh; Bellew, Donald R.; Prakash, G. K. Surya
Journal of Organic Chemistry, 1991 , vol. 56, # 3 p. 984 - 989
反应条件
1: chloro-trimethyl-silane With magnesium in N,N-dimethyl-formamide T=0°C; 2: 4-trifluoromethylsulfonyl benzene in N,N-dimethyl-formamide T=0 - 20°C;
参考文献
Prakash, G.K. Surya; Hu, Jinbo; Olah, George A.
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4457 - 4463
反应条件
1: chloro-trimethyl-silane With magnesium in N,N-dimethyl-formamide T=0°C; 0.0333333 h; 2: PhSOCF3 in N,N-dimethyl-formamide T=0 - 20°C; 2 h;
参考文献
Prakash, G.K. Surya; Hu, Jinbo; Olah, George A.
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4457 - 4463
反应条件
tetrabutyl ammonium fluoride in N,N-dimethyl-formamide T=20 - 140°C; Product distribution / selectivity;
参考文献
US2007/276149 A1, ;
Page/Page column 5-6 ;
反应条件
magnesium in N,N-dimethyl-formamide T=20°C; 20 h;
参考文献
Prakash, G.K. Surya; Hu, Jinbo; Olah, George A.
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4457 - 4463
反应条件
1: chloro-trimethyl-silane With magnesium in N,N-dimethyl-formamide T=0°C; 2: phenyl trifluoromethyl sulphide in N,N-dimethyl-formamide T=20°C; 4 h;
参考文献
Prakash, G.K. Surya; Hu, Jinbo; Olah, George A.
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4457 - 4463
反应条件
in anhydrous butyl ether 2 h; Ambient temperature;
参考文献
Beckers, H.; Buerger, H.; Bursch, P.; Ruppert, I.
Journal of Organometallic Chemistry, 1986 , vol. 316, p. 41 - 50
参考文献
Ruppert, Ingo; Schlich, Klaus; Volbach, Wolfgang
Tetrahedron Letters, 1984 , vol. 25, # 21 p. 2195 - 2198
