(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
[PdBr2(PPh3)2] T=100°C; 20 h;
参考文献
Journal of Organometallic Chemistry, , vol. 225, # 1 p. 331 - 342
参考文献
Journal of Fluorine Chemistry, , vol. 29, p. 98
反应条件
1-methyl-pyrrolidin-2-one; potassium fluoride; copper(l) iodide in N,N-dimethyl-formamide T=80°C;
参考文献
Kitazume, Tomoya; Nakajima, Satoshi
Journal of Fluorine Chemistry, 2004 , vol. 125, # 10 p. 1447 - 1449
反应条件
1: (trifluoromethyl)-trimethylsilane With silver monofluoride in various solvent(s) T=20°C; 2 h; 2: 2-chloro-3-pyridinecarboxylic acid chloride in various solvent(s) T=20°C; 12 h; Further stages.;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Naumann, Dieter; Fischer, Hendrik T.M.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1385 - 1389
反应条件
1: With potassium carbonate in N,N-dimethyl-formamide T=20°C; 4 h; 2: With water in N,N-dimethyl-formamide 4 h; Acidic conditions;
参考文献
Cheng, Huicheng; Pei, Yu; Leng, Faqiang; Li, Jingya; Liang, Apeng; Zou, Dapeng; Wu, Yangjie; Wu, Yusheng
Tetrahedron Letters, 2013 , vol. 54, # 33 p. 4483 - 4486
反应条件
1: in tetrahydrofuran T=0°C; 0.166667 h; Inert atmosphereSealed tube; 2: With tetrabutyl ammonium fluoride in tetrahydrofuran T=0 - 20°C; Inert atmosphereSealed tube; 3: With tetrabutyl ammonium fluoride; water in tetrahydrofuran T=0 - 20°C; Inert atmosphereSealed tube;
参考文献
Journal of Organic Chemistry, , vol. 77, # 18 p. 8131 - 8141
反应条件
potassium fluoride; copper(l) iodide; 1,10-phenanthroline; oxygen in N,N-dimethyl-formamide T=100°C; P=760.051 Torr; 6 h;
参考文献
Jiang, Xueliang; Chu, Lingling; Qing, Feng-Ling
Journal of Organic Chemistry, 2012 , vol. 77, # 3 p. 1251 - 1257
反应条件
potassium fluoride in N,N-dimethyl acetamide T=50°C; Title compound not separated from byproducts;
参考文献
Adams, Dave J.; Clark, James H.; Hansen, Liv B.; Sanders, Victoria C.; Tavener, Stewart J.
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 18 p. 3081 - 3085
反应条件
15-crown-5; cesium fluoride in ethylene glycol dimethyl ether T=-18 - 20°C; 1 h;
参考文献
Tyrra, Wieland; Naumann, Dieter; Quadt, Silke; Buslei, Sigrid; Yagupolskii, Yurii L.; Kremlev, Mikhail M.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 813 - 817
反应条件
[Pd(η3-1-Ph-allyl)(μ-Cl)]2; cyclohexyl BrettPhos; sodium lauryl sulfate; cesium fluoride in toluene T=110°C; 12 h; Inert atmosphere;
参考文献
Samant, Bhupesh S.; Kabalka, George W.
Chemical Communications, 2011 , vol. 47, # 25 p. 7236 - 7238
