(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
1: (trifluoromethyl)-trimethylsilane With silver monofluoride in various solvent(s) T=20°C; 2 h; 2: 4-methoxy-benzoyl chloride in various solvent(s) T=20°C; 12 h; Further stages.;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Naumann, Dieter; Fischer, Hendrik T.M.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1385 - 1389
反应条件
1: With tetra-n-butylammonium acetate in toluene T=0 - 20°C; 1 h; 2: With hydrogenchloride in tetrahydrofuran; toluene
参考文献
Kawano, Yoshikazu; Kaneko, Nobuya; Mukaiyama, Teruaki
Bulletin of the Chemical Society of Japan, 2006 , vol. 79, # 7 p. 1133 - 1145
反应条件
1: p-acetylbenzenediazonium tetrafluoroborate With copper(I) isothiocyanate; sodium isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane in acetonitrile T=20°C; 16 h;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Chemical Science, 2014 , vol. 5, # 4 p. 1312 - 1316
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran T=20°C;
参考文献
Furin, G. G.; Bardin, V. V.
Journal of Fluorine Chemistry, 1991 , vol. 54, # 1-3 p. 242
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper (I) trifluoromethane sulfonate benzene; silver carbonate in N,N-dimethyl-formamide T=45°C; Inert atmosphere;
参考文献
Chu, Lingling; Qing, Feng-Ling
Organic Letters, 2010 , vol. 12, # 21 p. 5060 - 5063
反应条件
1: (trifluoromethyl)-trimethylsilane With 1,10-phenanthroline; potassium tert-butylate; copper(l) chloride in N,N-dimethyl-formamide T=20°C; 1.5 h; Inert atmosphere; 2: 4'-iodoacetophenone in N,N-dimethyl-formamide T=50°C; 18 h; Inert atmosphere; Product distribution / selectivity;
参考文献
THE BOARD OF TRUSTESS OF THE UNIVERSITY OF ILLINOIS; HARTWIG, John, F.; MORIMOTO, Hiroyuki; FIER, Patrick
Patent: WO2012/24564 A1, 2012 ;
Location in patent: Page/Page column 7; 35-36 ;
反应条件
1,10-phenanthroline; oxygen; cesium fluoride; copper dichloride in 1,2-dichloro-ethane T=20°C; Chan-Lam-type reaction; P=760.051 Torr; Molecular sieveInert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 4 p. 1174 - 1176
反应条件
1: 3-acetylbenzenediazonium tetrafluoroborate With copper(I) isothiocyanate; sodium isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane in acetonitrile T=20°C; 16 h;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Chemical Science, 2014 , vol. 5, # 4 p. 1312 - 1316
反应条件
cesium fluoride in tetrahydrofuran T=20°C; Silylation; 1.5 h;
参考文献
Ishizaki, Miyuki; Hoshino, Osamu
Tetrahedron, 2000 , vol. 56, # 45 p. 8813 - 8819
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Organic Letters, , vol. 13, # 20 p. 5464 - 5467
