(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
copper(l) iodide; silver fluoride; sodium t-butanolate; N-methyl-2-(methylamino)ethylamine in 1-methyl-pyrrolidin-2-one T=20 - 90°C; 5.5 h; Inert atmosphere;
参考文献
Weng, Zhiqiang; Lee, Richmond; Jia, Weiguo; Yuan, Yaofeng; Wang, Wenfeng; Feng, Xue; Huang, Kuo-Wei
Organometallics, 2011 , vol. 30, # 11 p. 3229 - 3232
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: 2-Methylbenzenediazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
tetramethyl-ammonium fluoride in ethylene glycol dimethyl ether T=-30 - 20°C;
参考文献
Babadzhanova; Kirij; Yagupolskii; Tyrra; Naumann
Tetrahedron, 2005 , vol. 61, # 7 p. 1813 - 1819
反应条件
potassium fluoride in acetonitrile 18 h; -40 deg C to r.t.;
参考文献
Kotun, Stefan P.; Anderson, John D. O.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1124 - 1131
反应条件
potassium fluoride in acetonitrile a) 9 h, -40 deg C, b) 3 h, 18 deg C; other carbonyl compounds, variation of conditions: xfluorinated tertiary alcohols and alkoxides from nucleophilic trifluoromethylation of carbonyl compounds; Mechanism;
参考文献
Kotun, Stefan P.; Anderson, John D. O.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1124 - 1131
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran T=20°C;
参考文献
Furin, G. G.; Bardin, V. V.
Journal of Fluorine Chemistry, 1991 , vol. 54, # 1-3 p. 242
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper (I) trifluoromethane sulfonate benzene; silver carbonate in N,N-dimethyl-formamide T=45°C; Inert atmosphere;
参考文献
Chu, Lingling; Qing, Feng-Ling
Organic Letters, 2010 , vol. 12, # 21 p. 5060 - 5063
反应条件
1: 1-(biphenyl-1-yl)-3,3-diiospropyltriaz-1-ene With methyl iodide T=110°C; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane With potassium fluoride; copper(l) iodide in 1-methyl-pyrrolidin-2-one T=60°C; 16 h; Inert atmosphere;
参考文献
Hafner, Andreas; Braese, Stefan
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 5 p. 996 - 1000
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran; pentane 72 h; Ambient temperature;
参考文献
Wiedemann, Juergen; Heiner, Thomas; Mloston, Gregorz; Prakash, G.K. Surya; Olah, George A.
Angewandte Chemie - International Edition, 1998 , vol. 37, # 6 p. 820 - 821
反应条件
potassium fluoride in acetonitrile 14 h; -25 to 20 deg C;
参考文献
Kotun, Stefan P.; Anderson, John D. O.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1124 - 1131
