(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
nitrosyl chloride; cesium fluoride in ethylene glycol dimethyl ether T=-196 - 25°C; 3 h;
参考文献
Singh, Rajendra P.; Shreeve, Jean'ne M.
Chemical Communications, 2002 , # 17 p. 1818 - 1819
反应条件
in tetrahydrofuran byproducts: Me3SiOCH(CF3)2; (N2 or Ar); stirred at 50°C for 12 h; evapd. (vac.), washed (cold hexane), dried (vac.), recrystd. (THF); elem. anal.;
参考文献
Usui, Yoko; Noma, Junko; Hirano, Masafumi; Komiya, Sanshiro
Inorganica Chimica Acta, 2000 , vol. 309, # 1-2 p. 151 - 154
反应条件
in methanol mixt. of CuF2*3H2O and PPh3 in MeOH stirred under reflux in air overnight, filtration, filtrate evapd. to dryness under vac., residue dried under vac. overnight, treated with THF and CF3SiMe3 in glove box, mixt. stirred under Ar for 2 h; solid quickly filtered off in air, washed successively with dry THF and hexane, dried under vac.;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
in tetrahydrofuran byproducts: Me3SiOPh; (N2 or Ar); at 50°C for 12 h; elem. anal.;
参考文献
Usui, Yoko; Noma, Junko; Hirano, Masafumi; Komiya, Sanshiro
Inorganica Chimica Acta, 2000 , vol. 309, # 1-2 p. 151 - 154
反应条件
copper diacetate; triethylamine; cesium fluoride in 1,2-dichloro-ethane T=20°C; Chan-Lam-type reaction; P=760.051 Torr; Molecular sieveInert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 4 p. 1174 - 1176
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper (I) cyanide in N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Organic Letters, , vol. 12, # 21 p. 5060 - 5063
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper(I) bromide in N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Organic Letters, , vol. 12, # 21 p. 5060 - 5063
反应条件
potassium fluoride; potassium phosphate; copper(l) iodide; 1,10-phenanthroline in N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Organic Letters, , vol. 12, # 21 p. 5060 - 5063
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper(l) chloride in N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Organic Letters, , vol. 12, # 21 p. 5060 - 5063
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: 1H-indole-5-diazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
