(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
1: (trifluoromethyl)-trimethylsilane With silver fluoride in N,N-dimethyl-formamide T=20°C; 0.333333 h; 2: With copper in N,N-dimethyl-formamide 4 h; 3: 2,6-Dibromopyridine in N,N-dimethyl-formamide T=75°C; 4 h;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Yagupolskii, Yurii L.; Naumann, Dieter; Moeller, Angela
Journal of Fluorine Chemistry, 2012 , vol. 133, p. 67 - 71
反应条件
1: cyano derivative of benzenediazonium tetrafluoroborate With copper(I) isothiocyanate; sodium isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane in acetonitrile T=20°C; 16 h;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Chemical Science, 2014 , vol. 5, # 4 p. 1312 - 1316
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=20°C; 24 h; Molecular sieveInert atmosphere;
参考文献
Chen, Chao; Xie, Yan; Chu, Lingling; Wang, Ruo-Wen; Zhang, Xingang; Qing, Feng-Ling
Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2492 - 2495
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran 30 min at -25 deg C, then slowly warmed up to 10 deg C (total time 2 h);
参考文献
Movchun, Valeria N.; Kolomeitsev, Alexander A.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 255 - 258
反应条件
[bis(acetoxy)iodo]benzene; silver fluoride in dimethyl sulfoxide T=20°C; 20 h;
参考文献
Seo, Sangwon; Taylor, John B.; Greaney, Michael F.
Chemical Communications, 2013 , vol. 49, # 57 p. 6385 - 6387
反应条件
1: With tetra-n-butylammonium acetate in toluene T=0 - 20°C; 1 h; 2: With hydrogenchloride in tetrahydrofuran; toluene 16 h;
参考文献
Kawano, Yoshikazu; Kaneko, Nobuya; Mukaiyama, Teruaki
Bulletin of the Chemical Society of Japan, 2006 , vol. 79, # 7 p. 1133 - 1145
反应条件
1: (trifluoromethyl)-trimethylsilane With silver monofluoride T=20°C; 2 h; 2: 4-chloro-benzoyl chloride With 4-(N,N-dimethlyamino)pyridine in dichloromethane T=20°C; 48 h; Further stages.;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Naumann, Dieter; Fischer, Hendrik T.M.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1385 - 1389
反应条件
1: With tetra-n-butylammonium acetate in toluene T=0 - 20°C; 1 h; 2: With hydrogenchloride in tetrahydrofuran; toluene
参考文献
Kawano, Yoshikazu; Kaneko, Nobuya; Mukaiyama, Teruaki
Bulletin of the Chemical Society of Japan, 2006 , vol. 79, # 7 p. 1133 - 1145
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in pentane 30 min at 0 - 2 deg C, then slowly warmed up to 20 deg C (total time 2 h);
参考文献
Movchun, Valeria N.; Kolomeitsev, Alexander A.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 255 - 258
反应条件
1: 1-(4-chlorophenyl)diazonium tetrafluoroborate With copper(I) isothiocyanate; sodium isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane in acetonitrile T=20°C; 16 h;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Chemical Science, 2014 , vol. 5, # 4 p. 1312 - 1316
