(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Ye, Yingda; Lee, Shin Hee; Sanford, Melanie S.
Organic Letters, 2011 , vol. 13, # 20 p. 5464 - 5467
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: 4-Iodobenzenediazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
potassium fluoride; copper(l) iodide; N-(EtOCH2CH2OCH2)-N-methylmorpholinium bis(CF3SO2)amide T=80°C; 8 h;
参考文献
Kim, Jinwi; Shreeve, Jean'ne M.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 19 p. 2728 - 2734
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: quinoline-6-diazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
1-methyl-pyrrolidin-2-one; potassium fluoride; copper(l) iodide
参考文献
Cottet, Fabrice; Schlosser, Manfred
Tetrahedron, 2004 , vol. 60, # 51 p. 11869 - 11874
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Ye, Yingda; Lee, Shin Hee; Sanford, Melanie S.
Organic Letters, 2011 , vol. 13, # 20 p. 5464 - 5467
反应条件
1: With C52H46I2O8; potassium phenolate in toluene T=-50°C; 1 h; Inert atmosphere; 2: With hydrogenchloride in tetrahydrofuran; water T=20°C; optical yield given as percent eeenantioselective reaction;
参考文献
Wu, Shaoxiang; Guo, Jiyi; Sohail, Muhammad; Cao, Chengyao; Chen, Fu-Xue
Journal of Fluorine Chemistry, 2013 , vol. 148, p. 19 - 29
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran; water T=0 - 20°C;
参考文献
Dyke, Alan M.; Gill, Duncan M.; Harvey, Jeremy N.; Hester, Alison J.; Lloyd-Jones, Guy C.; Munoz, M. Paz; Shepperson, Ian R.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 27 p. 5067 - 5070
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 0 deg C, 5 min then rt., 2.5 h;
参考文献
Billard, Thierry; Large, Sylvie; Langlois, Bernard R.
Tetrahedron Letters, 1997 , vol. 38, # 1 p. 65 - 68
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 0 deg C, 1 h, RT;
参考文献
Billard, Thierry; Langlois, Bernard R.
Tetrahedron Letters, 1996 , vol. 37, # 38 p. 6865 - 6868
