(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
1: 1-(2,6-dimethylphenyl)-3,3-diisopropyltriaz-1-ene With methyl iodide
T=110°C; Inert atmosphere;
2: (trifluoromethyl)-trimethylsilane With potassium fluoride; copper(l) iodide in 1-methyl-pyrrolidin-2-one
T=60°C; 16 h; Inert atmosphere;
参考文献
Hafner, Andreas; Braese, Stefan
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 5 p. 996 - 1000
反应条件
tetramethyl-ammonium fluoride
T=-50°C; 0.5 h; Inert atmosphere;
参考文献
Behr, Jean-Bernard; Chavaria, Dani; Plantier-Royon, Richard
Journal of Organic Chemistry, 2013 , vol. 78, # 22 p. 11477 - 11482
反应条件
15-crown-5; cesium fluoride in ethylene glycol dimethyl ether
T=-18 - 20°C; 1 h;
参考文献
Tyrra, Wieland; Naumann, Dieter; Quadt, Silke; Buslei, Sigrid; Yagupolskii, Yurii L.; Kremlev, Mikhail M.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 813 - 817
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran
T=-10°C; 1 h;
参考文献
Sevenard; Kirsch; Roeschenthaler; Movchun; Kolomeitsev
Synlett, 2001 , # 3 p. 379 - 381
反应条件
potassium fluoride; copper(l) iodide; N-(EtOCH2CH2OCH2)-N-methylmorpholinium bis(CF3SO2)amide
T=80°C; 8 h;
参考文献
Kim, Jinwi; Shreeve, Jean'ne M.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 19 p. 2728 - 2734
