(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: m-carboxybenzenediazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
[bis(acetoxy)iodo]benzene; silver fluoride in dimethyl sulfoxide T=20°C; 20 h;
参考文献
Seo, Sangwon; Taylor, John B.; Greaney, Michael F.
Chemical Communications, 2013 , vol. 49, # 57 p. 6385 - 6387
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=20°C; 24 h; Molecular sieveInert atmosphere;
参考文献
Chen, Chao; Xie, Yan; Chu, Lingling; Wang, Ruo-Wen; Zhang, Xingang; Qing, Feng-Ling
Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2492 - 2495
反应条件
1: 4-toluenediazonium tetrafluoroborate With copper(I) isothiocyanate; sodium isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane in acetonitrile T=20°C; 16 h;
参考文献
Chemical Science, , vol. 5, # 4 p. 1312 - 1316
反应条件
1: (trifluoromethyl)-trimethylsilane With silver fluoride in anhydrous propionitrile T=20°C; 0.333333 h; 2: With copper in anhydrous propionitrile 4 h; 3: 4-bromo-benzoic acid ethyl ester in anhydrous propionitrile T=20°C; Heating;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Yagupolskii, Yurii L.; Naumann, Dieter; Moeller, Angela
Journal of Fluorine Chemistry, 2012 , vol. 133, p. 67 - 71
反应条件
1: C15H23N3O2 With methyl iodide T=110°C; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane With potassium fluoride; copper(l) iodide in 1-methyl-pyrrolidin-2-one T=60°C; 16 h; Inert atmosphere;
参考文献
Hafner, Andreas; Braese, Stefan
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 5 p. 996 - 1000
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: 4-acetamidobenzenediazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
[bis(acetoxy)iodo]benzene; silver fluoride in dimethyl sulfoxide T=20°C; 20 h;
参考文献
Seo, Sangwon; Taylor, John B.; Greaney, Michael F.
Chemical Communications, 2013 , vol. 49, # 57 p. 6385 - 6387
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Ye, Yingda; Lee, Shin Hee; Sanford, Melanie S.
Organic Letters, 2011 , vol. 13, # 20 p. 5464 - 5467
反应条件
copper(l) iodide; silver fluoride; sodium t-butanolate; N-methyl-2-(methylamino)ethylamine in 1-methyl-pyrrolidin-2-one T=20 - 90°C; 5.5 h; Inert atmosphere;
参考文献
Weng, Zhiqiang; Lee, Richmond; Jia, Weiguo; Yuan, Yaofeng; Wang, Wenfeng; Feng, Xue; Huang, Kuo-Wei
Organometallics, 2011 , vol. 30, # 11 p. 3229 - 3232
