(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=20°C; 24 h; Molecular sieveInert atmosphere;
参考文献
Chen, Chao; Xie, Yan; Chu, Lingling; Wang, Ruo-Wen; Zhang, Xingang; Qing, Feng-Ling
Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2492 - 2495
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 0 deg C, 5 min then rt., 2.5 h;
参考文献
Billard, Thierry; Large, Sylvie; Langlois, Bernard R.
Tetrahedron Letters, 1997 , vol. 38, # 1 p. 65 - 68
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in pentane 30 min at 0 - 2 deg C, then slowly warmed up to 20 deg C (total time 2 h);
参考文献
Movchun, Valeria N.; Kolomeitsev, Alexander A.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 255 - 258
反应条件
potassium fluoride; potassium phosphate; copper(l) iodide; 1,10-phenanthroline; sulfur; silver carbonate in N,N-dimethyl-formamide T=20°C; Molecular sieve;
参考文献
Chen, Chao; Xie, Yan; Chu, Lingling; Wang, Ruo-Wen; Zhang, Xingang; Qing, Feng-Ling
Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2492 - 2495
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 0 deg C, 1 h, RT;
参考文献
Billard, Thierry; Langlois, Bernard R.
Tetrahedron Letters, 1996 , vol. 37, # 38 p. 6865 - 6868
反应条件
(Me2N)2S+Me3SiF2- in Petroleum ether T=25°C; 1 h;
参考文献
Kolomeitsev; Movchun; Kondratenko; Yagupolski
Synthesis, 1990 , # 12 p. 1151 - 1152
反应条件
1: (trifluoromethyl)-trimethylsilane With silver monofluoride in various solvent(s) T=20°C; 2 h; 2: 4-methyl-benzoyl chloride in various solvent(s) T=20°C; 12 h; Further stages.;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Naumann, Dieter; Fischer, Hendrik T.M.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1385 - 1389
反应条件
1,10-phenanthroline; oxygen; copper diacetate; cesium fluoride in iso-butyronitrile T=20°C; Chan-Lam-type reaction; P=760.051 Torr; 3 h; Molecular sieveInert atmosphere;
参考文献
Senecal, Todd D.; Parsons, Andrew T.; Buchwald, Stephen L.
Journal of Organic Chemistry, 2011 , vol. 76, # 4 p. 1174 - 1176
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: 3-acetylbenzenediazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
15-crown-5; cesium fluoride in ethylene glycol dimethyl ether T=-18 - 20°C; 1 h;
参考文献
Tyrra, Wieland; Naumann, Dieter; Quadt, Silke; Buslei, Sigrid; Yagupolskii, Yurii L.; Kremlev, Mikhail M.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 813 - 817
