3,2′:5′,3″-三噻吩合成路线 （共 7 条）
反应条件
sodium sulfide in methanol
Heating;
参考文献
Beny, Jean-Pierre; Dhawan, Som N.; Kagan, Jacques; Sundlass, Satinder
Journal of Organic Chemistry, 1982 , vol. 47, # 11 p. 2201 - 2204
反应条件
diphosphorus pentasulfide; sodium hydrogencarbonate in dichloromethane
Ambient temperature;
参考文献
Moriarty, Robert M.; Prakash, Om; Duncan, Michael P.
Synthetic Communications, 1985 , vol. 15, # 9 p. 789 - 796
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate in ethylene glycol dimethyl ether
4 h; Heating;
参考文献
Gronowitz, Salo; Peters, Dan
Heterocycles, 1990 , vol. 30, # 1 p. 645 - 658
反应条件
bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide
Condensation; 20 h; Heating;
参考文献
Al-Taweel, Samir A.; Al-Saraierh, Hassan F.
Phosphorus, Sulfur and Silicon and Related Elements, 1999 , vol. 155, p. 47 - 57
反应条件
1: 73 percent / CuCl, N,N,N',N'-tetramethylethylenediamine, air / 1,2-dimethoxy-ethane / 1 h / 30 - 35 °C
2: 100 percent / Na2S*9H2O / methanol / Heating
View Scheme
参考文献
Beny, Jean-Pierre; Dhawan, Som N.; Kagan, Jacques; Sundlass, Satinder
Journal of Organic Chemistry, 1982 , vol. 47, # 11 p. 2201 - 2204
反应条件
1: 56 percent / n-BuLi / diethyl ether / 1.) -78, 1 h, 2.) RT, 1 h
2: 73 percent / CuCl, N,N,N',N'-tetramethylethylenediamine, air / 1,2-dimethoxy-ethane / 1 h / 30 - 35 °C
3: 100 percent / Na2S*9H2O / methanol / Heating
View Scheme
参考文献
Beny, Jean-Pierre; Dhawan, Som N.; Kagan, Jacques; Sundlass, Satinder
Journal of Organic Chemistry, 1982 , vol. 47, # 11 p. 2201 - 2204
反应条件
in N,N-dimethyl-formamide
T=150°C; 1 h; Schlenk techniqueInert atmosphere;
参考文献
Tang, Jialiang; Ming, Ling; Zhao, Xiaoming
Synthesis (Germany), 2013 , vol. 45, # 12 art. no. SS-2013-H0207-OP, p. 1713 - 1718
