tetrabutylammonium trifluoromethanesulphonate in methanol electrolysis;

1.1: acetonitrile / 20 °C / Electrochemical reaction; Undivided electrochemical cell with aluminum anode/platinum cathode; Inert atmosphere 1.2: Inert atmosphere; Cooling with ice 2.1: oxalyl dichloride; tetrabutylammonium trifluoromethanesulphonate / acetonitrile / 0.17 h / 20 °C / Inert atmosphere View Scheme

water

1: in acetonitrile T=20°C; Electrochemical reactionUndivided electrochemical cell with aluminum anode/platinum cathodeInert atmosphere; 2: With hydrogenchloride; water in acetonitrile Inert atmosphereCooling with ice;

1: Bu4NCF3SO3 / methanol / electrolysis 2: 83 percent / P4S10 / 2 h / 200 °C 3: 80 percent / CHCl3 / 3 h / Heating 4: 86 percent / LiCl / methanol / electrolysis View Scheme

tetrabutylammonium trifluoromethanesulphonate in methanol electrolysis;

1: in acetonitrile T=20°C; Electrochemical reactionUndivided electrochemical cell with aluminum anode/platinum cathodeInert atmosphere; 2: With hydrogenchloride; water in acetonitrile Inert atmosphereCooling with ice;

tetrabutylammonium trifluoromethanesulphonate in methanol electrolysis;

water