3-溴-1-甲基-1H-吲哚合成路线 （共 18 条）
反应条件
sodium tetrahydroborate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran T=20°C; 19 h; Inert atmosphere; Reagent/catalystTime;
参考文献
Chelucci, Giorgio; Baldino, Salvatore; Ruiu, Andrea
Journal of Organic Chemistry, 2012 , vol. 77, # 21 p. 9921 - 9925,5
反应条件
triethylamine; tris-(o-tolyl)phosphine; palladium diacetate T=100°C; Heck reaction; 24 h;
参考文献
Synlett, , # 9 p. 1319 - 1322
反应条件
tetrabutylammomium bromide; water; copper(ll) bromide in 1,2-dichloro-ethane T=20°C; 1 h;
参考文献
Tang, Shi; Li, Jin-Heng; Xie, Ye-Xiang; Wang, Nai-Xing
Synthesis, 2007 , # 10 p. 1535 - 1541
反应条件
bromine in N,N-dimethyl-formamide
Ambient temperature;
参考文献
Bocchi, Vittorio; Palla, Gerardo
Synthesis, 1982 , # 12 p. 1096 - 1097
反应条件
silver carbonate; copper(ll) bromide; palladium dichloride in tetrahydrofuran
T=110°C; 24 h;
参考文献
Peng, Xuefeng; Shao, Xiang-Feng; Liu, Zhong-Quan
Tetrahedron Letters, 2013 , vol. 54, # 24 p. 3079 - 3081
反应条件
1: With tert.-butyl lithium in tetrahydrofuran; hexane
T=-78°C; 0.0833333 h;
2: With water; ammonium chloride in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Liu, Yanbing; Gribble, Gordon W
Tetrahedron Letters, 2002 , vol. 43, # 40 p. 7135 - 7137
反应条件
sodium hydroxide; silica gel; copper(ll) bromide in 1,2-dichloro-ethane
T=20°C; 0.25 h;
参考文献
Tang, Shi; Li, Jin-Heng; Xie, Ye-Xiang; Wang, Nai-Xing
Synthesis, 2007 , # 10 p. 1535 - 1541
反应条件
copper(I) bromide dimethylsulfide complex in acetonitrile
T=70°C; 16 h; Schlenk techniqueInert atmosphere;
参考文献
John, Alex; Nicholas, Kenneth M.
Organometallics, 2012 , vol. 31, # 22 p. 7914 - 7920
反应条件
copper(I) bromide dimethylsulfide complex in acetonitrile
T=70°C; 16 h; Schlenk techniqueInert atmosphere;
参考文献
John, Alex; Nicholas, Kenneth M.
Organometallics, 2012 , vol. 31, # 22 p. 7914 - 7920
反应条件
1.1: sodium hydride / tetrahydrofuran; mineral oil / 1.42 h / 0 - 20 °C / |Inert atmosphere
1.2: 0.5 h / 0 - 20 °C / |Inert atmosphere
2.1: N-bromosuccinmide / tetrahydrofuran / 6 h / -78 °C / |Inert atmosphere
View Scheme
参考文献
Saha, Debajyoti; Ghosh, Raju; Sarkar, Amitabha
Tetrahedron, 2013 , vol. 69, # 19 p. 3951 - 3960
