反应条件
1.1: sodium hydroxide; sodium tetrahydroborate / water / 16.5 h / 0 - 20 °C / |Inert atmosphere; |Schlenk technique 1.2: |Inert atmosphere; |Schlenk technique 2.1: acetyl chloride / 4 h / 65 °C / |Inert atmosphere; |Schlenk technique 3.1: sodium hydride / mineral oil; tetrahydrofuran; N,N-dimethyl-formamide / 0.33 h / 0 °C / |Inert atmosphere; |Schlenk technique 3.2: 3 h / 0 - 20 °C / |Inert atmosphere; |Schlenk technique 4.1: lithium aluminium tetrahydride / diethyl ether / 3 h / 0 - 20 °C / |Inert atmosphere; |Schlenk technique 5.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.5 h / -78 °C / |Inert atmosphere; |Schlenk technique 5.2: 1 h / -78 - 20 °C / |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Nitsch, Dominik; Huber, Stefan M.; Poethig, Alexander; Narayanan, Arjun; Olah, George A.; Prakash, G. K. Surya; Bach, Thorsten
Journal of the American Chemical Society, 2014 , vol. 136, # 7 p. 2851 - 2857
