3-甲基-2,4-戊烷二酮合成路线 (共 94 条)
反应条件
P(MeNCH2CH2)3N in hexane; acetonitrile T=25°C; 0.5 h;
参考文献
Arumugam, Subramaniam; McLeod, Dale; Verkade, John G.
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3677 - 3679
反应条件
in α-cyanoacetic acid methyl ester
参考文献
Bayer Aktiengesellschaft
Patent: US4567004 A1, 1986 ;
反应条件
carbon monoxide; hydrogen; tri-ruthenium(0)dodecacarbonyl in N,N-dimethyl-formamide T=150°C; P=76000.1 Torr; 16 h;
参考文献
Abe, Fujio; Hayashi, Teruyuki; Tanaka, Masato
Chemistry Letters, 1990 , # 5 p. 765 - 768
反应条件
sodium dichromate; sulfuric acid in acetone
参考文献
Journal of the American Chemical Society, , vol. 108, # 8 p. 2094 - 2096
反应条件
sodium hypochlorite; 1-oxyl-2,2,6,6-tetramethlpiperidin-4-yl benzoate; sodium hydrogencarbonate; potassium bromide in dichloromethane; water T=5°C; 2 h;
参考文献
Organic Process Research and Development, , vol. 6, # 5 p. 628 - 631
反应条件
potassium carbonate in acetone T=20°C; 120 h;
参考文献
Dalton Transactions, , vol. 42, # 34 p. 12265 - 12273
反应条件
sodium hydride in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=20°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chemische Berichte, , vol. 114, # 8 p. 2866 - 2883
反应条件
sodium hydride in dimethyl sulfoxide 13 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 553 - 555
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 224, p. 1234
反应条件
9,10-dihydro-anthracene in 1,3,5-trimethyl-benzene T=230°C; different temperatures; ΔG(excit.)300, ΔH(excit.), ΔS(excit.); KineticsRate constant;
参考文献
Noelke, Margot; Verevkin, Sergej P.; Beckhaus, Hans-Dieter; Ruechardt, Christoph
Liebigs Annalen, 1995 , # 1 p. 41 - 52