反应条件
1: 97 percent / aq.OsO4, KIO4 / tetrahydrofuran; H2O / 16 h / Ambient temperature 2: 85 percent / 90percent H2O2, trifluoroacetic anhydride, KH2PO4 / CH2Cl2 / 0 °C 3: cation exchange resin AG 50W-X4 / ethanol / 50 °C 4: NaOEt / ethanol / 2 h / Ambient temperature 5: 95 percent / imidazole / dimethylformamide / Ambient temperature 6: 81 percent / (Ph2)S<OC(CF3)2Ph>2 / CCl4 / 0.25 h 7: 88 percent / 9-fluorenone / various solvent(s) / 0.5 h / Irradiation 8: 92 percent / diisobutylaluminium hydride / toluene / 0.5 h / -78 °C 9: 91 percent / N-chlorosuccinimide, dimethyl sulfide / CH2Cl2 / 0.5 h / -20 °C 10: 2.) 5percent H2O2 / 1.) THF, -70 deg C, 2.) CH2Cl2, 1 h 11: 1.) n-BuLi / 1.) THF, n-hexane, -78 deg C, 5 min, 2.) THF, n-hexane, -78 deg C, 2 h View Scheme
参考文献
Baggiolini, Enrico G.; Iacobelli, Jerome A.; Hennessy, Bernard M.; Uskokovic, Milan R.
Journal of the American Chemical Society, 1982 , vol. 104, # 10 p. 2945 - 2948
