4,6-二甲基-1-庚醇合成路线 （共 18 条）
反应条件
1: POCl3 / pyridine
3: HBr
4: acetic acid
5: (hydrolysis)
6: (catalytic hydrogenation)
View Scheme
参考文献
Julia,S. et al.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1961 , vol. 253, p. 678 - 680
反应条件
1: HBr
2: acetic acid
3: (hydrolysis)
4: (catalytic hydrogenation)
View Scheme
参考文献
Julia,S. et al.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1961 , vol. 253, p. 678 - 680
反应条件
1: NaNH2; benzene
2: toluene / Heating
3: diethyl ether / Heating
4: aq. HBr
5: AcOH / Heating
6: KOH / methanol / Heating
7: H2 / PtO2 / methanol
View Scheme
参考文献
Julia,S. et al.
Bulletin de la Societe Chimique de France, 1964 , p. 3207 - 3217
反应条件
potassium hydroxide in methanol
Heating;
参考文献
Julia,S. et al.
Bulletin de la Societe Chimique de France, 1964 , p. 3207 - 3217
反应条件
1.1: pyridine / CH2Cl2 / 0 °C
2.1: 94 percent / LiBr / acetone / 20 °C
3.1: Mg / tetrahydrofuran / 4 h / 20 °C
3.2: 87 percent / CuI / tetrahydrofuran / -20 °C
View Scheme
参考文献
Tang, Rong; Webster, Francis X.; Mueller-Schwarze, Dietland
Journal of Chemical Ecology, 1995 , vol. 21, # 11 p. 1745 - 1762
反应条件
hydrogen; platinum(IV) oxide
参考文献
Julia,M. et al.
Tetrahedron, Supplement, 1966 , vol. 8, p. 443 - 462
反应条件
1: aq. KOH
2: H2 / PtO2
View Scheme
参考文献
Julia,M. et al.
Tetrahedron, Supplement, 1966 , vol. 8, p. 443 - 462
反应条件
1: (i) aq. HBr, (ii) /BRN= 3595449/
2: aq. KOH
3: H2 / PtO2
View Scheme
参考文献
Julia,M. et al.
Tetrahedron, Supplement, 1966 , vol. 8, p. 443 - 462
