3-溴-5,6,7,8-四氢喹啉合成路线 （共 5 条）
反应条件
in chloroform
T=0 - 45°C; Diels-Alder reaction; 0.583333 h; regioselective reaction;
参考文献
Anderson, Erin D.; Boger, Dale L.
Journal of the American Chemical Society, 2011 , vol. 133, # 31 p. 12285 - 12292
反应条件
1: 77 percent / dicarbonyl(cyclopentadienyl)cobalt / m-xylene / Heating; Irradiation
2: 71 percent / Br2 / CCl4 / Ambient temperature
3: Me4N(1+)*F(1-)
View Scheme
参考文献
Brien, David J.; Naiman, Alaric; Vollhardt, K. Peter C.
Journal of the Chemical Society, Chemical Communications, 1982 , # 2 p. 133 - 134
反应条件
copper(ll) bromide in methanol; water
T=75°C; 4 h;
参考文献
Zhao, Le; Tsukano, Chihiro; Kwon, Eunsang; Takemoto, Yoshiji; Hirama, Masahiro
Angewandte Chemie - International Edition, 2013 , vol. 52, # 6 p. 1722 - 1725
Angew. Chem., 2013 , vol. 125, # 6 p. 1766 - 1769,4
反应条件
1: 71 percent / Br2 / CCl4 / Ambient temperature
2: Me4N(1+)*F(1-)
View Scheme
参考文献
Brien, David J.; Naiman, Alaric; Vollhardt, K. Peter C.
Journal of the Chemical Society, Chemical Communications, 1982 , # 2 p. 133 - 134
反应条件
1: bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 4,4'-di-tert-butyl-2,2'-dipyridyl / tetrahydrofuran / 11 h / 75 °C / |Inert atmosphere
2: copper(ll) bromide / methanol; water / 4 h / 75 °C
View Scheme
参考文献
Zhao, Le; Tsukano, Chihiro; Kwon, Eunsang; Takemoto, Yoshiji; Hirama, Masahiro
Angewandte Chemie - International Edition, 2013 , vol. 52, # 6 p. 1722 - 1725
Angew. Chem., 2013 , vol. 125, # 6 p. 1766 - 1769,4
