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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
82238-23-1
合成路线
(共 8 条)
82238-23-1
→
反应条件
30673-29-1
反应条件
sodium tetrahydroborate in ethanol; dichloromethane 0.5 h; Ambient temperature;
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110
917-64-6
magnesium,carbanide,iodide
+
82238-23-1
→
反应条件
30673-29-1
+
30571-15-4
反应条件
in diethyl ether; benzene 3 h; Heating;
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110
82238-23-1
+
13139-86-1
3-甲基-CBS-氧硼啶
→
反应条件
30673-29-1
+
41959-23-3
反应条件
in diethyl ether; benzene 3 h; Heating;
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110
82238-23-1
→
反应条件
82238-29-7
反应条件
1,4-diaza-bicyclo[2.2.2]octane in benzene Ambient temperature;
参考文献
Hori, Mikio; Kataoka, Tadashi; Shimizu, Hiroshi; Tomimatsu, Kiminori
Tetrahedron Letters, 1982 , vol. 23, # 8 p. 901 - 904
82238-23-1
+
82238-27-5
→
反应条件
82238-30-0
+
82238-29-7
+
82238-32-2
+
82238-31-1
反应条件
in toluene Heating;
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110
82238-23-1
→
反应条件
82238-30-0
反应条件
1: 83.8 percent / diethyl ether; benzene / 3 h / Heating 2: acetonitrile / 3 h / Ambient temperature; 1 eq. chloramine-B 3: 97 percent / DABCO / benzene / 24 h / Ambient temperature View Scheme
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110
82238-23-1
+
82238-27-5
→
反应条件
82238-30-0
+
82238-29-7
+
82238-32-2
+
82238-31-1
反应条件
in toluene Heating;
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110
82238-23-1
→
反应条件
52182-93-1
反应条件
1: 83.8 percent / diethyl ether; benzene / 3 h / Heating 2: acetonitrile / 3 h / Ambient temperature; 1 eq. chloramine-T 3: 92 percent / H2O/silica gel / ethyl acetate 4: 58.2 percent / 30 h / Heating View Scheme
参考文献
Tomimatsu, Kiminori; Kataoka, Tadashi; Shimizu, Hiroshi; Hori, Mikio
Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 97 - 110