3,4-二氢-2H-1,4-苯并噻嗪1,1-二氧化物合成路线 （共 14 条）
反应条件
sodium methylate in methanol
T=25°C; 0.166667 h;
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
反应条件
1: 84 percent / sodium methoxide / methanol / 3 h / Heating
2: 66 percent / 3 h / Heating
3: 81 percent / potassium t-butoxide / 2-methyl-propan-2-ol / 0.25 h / 45 °C
4: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight
5: 100 percent / sodium methoxide / methanol / 0.17 h / 25 °C
View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
反应条件
1: m-chloroperbenzoic acid / CH2Cl2 / 0 °C
2: methanol / 0.5 h
View Scheme
参考文献
Babudri, F.; Di Nunno, L.; Florio, S.
Tetrahedron Letters, 1983 , vol. 24, # 36 p. 3883 - 3886
反应条件
1: 85 percent / lithium diisopropylamide / tetrahydrofuran / -78 deg C, 30 min, then allowed to warm to rt.
2: m-chloroperbenzoic acid / CH2Cl2 / 0 °C
3: methanol / 0.5 h
View Scheme
参考文献
Babudri, F.; Di Nunno, L.; Florio, S.
Tetrahedron Letters, 1983 , vol. 24, # 36 p. 3883 - 3886
反应条件
1: 84 percent / pyridine / -10 °C
2: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight
3: 100 percent / sodium methoxide / methanol / 0.17 h / 25 °C
View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
反应条件
1: 66 percent / 3 h / Heating
2: 81 percent / potassium t-butoxide / 2-methyl-propan-2-ol / 0.25 h / 45 °C
3: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight
4: 100 percent / sodium methoxide / methanol / 0.17 h / 25 °C
View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
反应条件
1: 81 percent / potassium t-butoxide / 2-methyl-propan-2-ol / 0.25 h / 45 °C
2: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight
3: 100 percent / sodium methoxide / methanol / 0.17 h / 25 °C
View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
反应条件
1: 79 percent / ammonium molybdate, 30percent hydrogen peroxide / methanol; H2O / Ambient temperature; overnight
2: 100 percent / sodium methoxide / methanol / 0.17 h / 25 °C
View Scheme
参考文献
Florio, Saverio; Leng, John L.; Stirling, Charles J. M.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 237 - 240
反应条件
diborane in tetrahydrofuran
参考文献
Fatheree, D. M.; Deeg, G. L.; Matthews, D. B.; Russell, J. G.
Organic Magnetic Resonance, 1982 , vol. 18, # 2 p. 92 - 97
参考文献
Hromatka et al.
Monatshefte fuer Chemie, 1957 , vol. 88, p. 822,828
Full Text Show Details
Fusco; Palazzo
Gazzetta Chimica Italiana, 1951 , vol. 81, p. 735,741
