1: sodium tetraphenyl borate With Amberlite(R)IRA-900 resin in water 2: 2-Iodothiophene With palladium diacetate in N,N-dimethyl-formamide T=80°C; Suzuki-Miyaura coupling reaction; 3 h; Further stages.;
1: thien-2-yl-lithium With indium(III) chloride in tetrahydrofuran T=-78 - 20°C; 2: iodobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran Heating; Further stages.;
参考文献
Journal of Organic Chemistry, , vol. 72, # 9 p. 3589 - 3591