2-{[甲基(氧代)苯基-lambda6-硫代]氨基}-N-(2,4,6-三异丙基苄基)苯胺合成路线 （共 6 条）
反应条件
sodium tetrahydroborate; acetic acid in methanol
T=20°C;
参考文献
Langner, Martin; Bolm, Carsten
Angewandte Chemie - International Edition, 2004 , vol. 43, # 44 p. 5984 - 5987
反应条件
1: 89 percent / rac-BINAP; Cs2CO3 / Pd(OAc)2 / toluene / 24 h / 110 °C
2: 83 percent / aq. acetic acid; Fe / ethanol / 3 h / Heating
3: glacial acetic acid / methanol / 3 h / 20 °C
4: 1.14 g / NaBH4 / methanol / 20 °C
View Scheme
参考文献
Langner, Martin; Remy, Pauline; Bolm, Carsten
Chemistry - A European Journal, 2005 , vol. 11, # 21 p. 6254 - 6265
反应条件
1: 89 percent / rac-BINAP; Cs2CO3 / Pd(OAc)2 / toluene / 24 h / 110 °C
2: 83 percent / aq. acetic acid; Fe / ethanol / 3 h / Heating
3: glacial acetic acid / methanol / 3 h / 20 °C
4: 1.14 g / NaBH4 / methanol / 20 °C
View Scheme
参考文献
Langner, Martin; Remy, Pauline; Bolm, Carsten
Chemistry - A European Journal, 2005 , vol. 11, # 21 p. 6254 - 6265
反应条件
1: 83 percent / aq. acetic acid; Fe / ethanol / 3 h / Heating
2: glacial acetic acid / methanol / 3 h / 20 °C
3: 1.14 g / NaBH4 / methanol / 20 °C
View Scheme
参考文献
Langner, Martin; Remy, Pauline; Bolm, Carsten
Chemistry - A European Journal, 2005 , vol. 11, # 21 p. 6254 - 6265
反应条件
1: glacial acetic acid / methanol / 3 h / 20 °C
2: 1.14 g / NaBH4 / methanol / 20 °C
View Scheme
参考文献
Langner, Martin; Remy, Pauline; Bolm, Carsten
Chemistry - A European Journal, 2005 , vol. 11, # 21 p. 6254 - 6265
反应条件
1: CuI; CsOAc / dimethylsulfoxide / 12 h / 90 °C
2: Fe; AcOH / aq. ethanol / Heating
3: NaBH4; AcOH / methanol / 0 - 20 °C
View Scheme
参考文献
Langner, Martin; Remy, Pauline; Bolm, Carsten
Synlett, 2005 , # 5 art. no. G00205ST, p. 781 - 784
