1-甲基-3,4-二氢-1H-喹啉-2-酮合成路线 （共 34 条）
反应条件
1: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 6 h / 20 °C
2: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: sodium nitrite; hydrogenchloride / water / 10 °C
2: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 12 h / 35 °C
3: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: sodium nitrite; hydrogenchloride / water / 10 °C
2: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 6 h / 20 °C
3: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 8 h / 35 °C
2: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 36 h / 70 °C
2: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: sodium nitrite; hydrogenchloride / water / 10 °C
2: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 8 h / 35 °C
3: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: sodium nitrite; hydrogenchloride / water / 10 °C
2: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 36 h / 70 °C
3: hydrogen / methanol / 3 h / 20 °C / |Schlenk technique
View Scheme
参考文献
Liu, Baoqing; Fan, Yang; Gao, Yang; Sun, Chao; Xu, Cheng; Zhu, Jin
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 468 - 473
反应条件
1: C5H11O(1-)*Cs(1+); 2,2-dimethyl-propanol; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; silver hexafluoroantimonate / methanol / 24 h / 20 °C / |Schlenk technique; |Inert atmosphere
2: 5 Pd/C; NaH2PO2 / methanol; water / 10 h / |Reflux; |Schlenk technique
View Scheme
参考文献
Huang, Xiaolei; Huang, Jingsheng; Du, Chenglong; Zhang, Xingyi; Song, Feijie; You, Jingsong
Angewandte Chemie - International Edition, 2013 , vol. 52, # 49 p. 12970 - 12974
反应条件
sulfur dioxide in water
参考文献
Ignatchenko, A. V.; Terent'ev, P. B.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 3 p. 292 - 295
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , vol. 23, # 3 p. 348 - 351
反应条件
sulfur dioxide in water
sealed ampoule;
参考文献
Ignatchenko, A. V.; Terent'ev, P. B.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 3 p. 292 - 295
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , vol. 23, # 3 p. 348 - 351
