螺[4.5]癸烷-7,9-二酮合成路线 （共 7 条）
反应条件
sodium hypobromide T=0°C;
参考文献
Norris; Thorpe
Journal of the Chemical Society, 1921 , vol. 119, p. 1206
反应条件
1: in methanol
2 h; Heating;
2: With barium dihydroxide in methanol; water
24 h; Heating;
参考文献
Schank, Kurt; La Vecchia, Luigi; Lick, Carlo
Helvetica Chimica Acta, 2001 , vol. 84, # 7 p. 2071 - 2088
反应条件
1.1: O3/O2 / methanol / -78 - 0 °C
1.2: 70 percent / thiourea / methanol / 3 h
2.1: 72 percent / I2 / toluene / Heating
3.1: methanol / 2 h / Heating
3.2: 78 percent / Ba(OH)2 / methanol; H2O / 24 h / Heating
View Scheme
参考文献
Schank, Kurt; La Vecchia, Luigi; Lick, Carlo
Helvetica Chimica Acta, 2001 , vol. 84, # 7 p. 2071 - 2088
反应条件
1.1: 72 percent / I2 / toluene / Heating
2.1: methanol / 2 h / Heating
2.2: 78 percent / Ba(OH)2 / methanol; H2O / 24 h / Heating
View Scheme
参考文献
Schank, Kurt; La Vecchia, Luigi; Lick, Carlo
Helvetica Chimica Acta, 2001 , vol. 84, # 7 p. 2071 - 2088
反应条件
1: alcohol
2: aq. barium hydroxide solution
View Scheme
参考文献
Norris; Thorpe
Journal of the Chemical Society, 1921 , vol. 119, p. 1206
参考文献
Qudrat-I-Khuda
Journal of the Chemical Society, 1929 , p. 719
反应条件
permanganate(VII) ion; sodium carbonate
T=20°C;
参考文献
Norris; Thorpe
Journal of the Chemical Society, 1921 , vol. 119, p. 1206
