2-碘-1,1:3,1-三联苯合成路线 （共 19 条）
反应条件
1: 1.) aq.HCl, NaNO2, 2.) KI / 1.) from 0 deg C to 5 deg C, 30 min, 2.) 1 h
2: 2.) I2 / 1.) THF, RT, 3 h, 2.) THF
View Scheme
参考文献
Du, Chi-Jen Frank; Hart, Harold; Ng, Kwok-Keung Daniel
Journal of Organic Chemistry, 1986 , vol. 51, # 16 p. 3162 - 3165
反应条件
iodine
1.) THF, RT, 3 h, 2.) THF; Yield given. Multistep reaction;
参考文献
Du, Chi-Jen Frank; Hart, Harold; Ng, Kwok-Keung Daniel
Journal of Organic Chemistry, 1986 , vol. 51, # 16 p. 3162 - 3165
反应条件
sulfuric acid; potassium iodide; sodium nitrite
Yield given. Multistep reaction;
参考文献
Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581
反应条件
iodine
1.) Et2O, RT, 15 h, 2.) Et2O; Yield given. Multistep reaction;
参考文献
Saednya, Akbar; Hart, Harold
Synthesis, 1996 , # 12 p. 1455 - 1458
反应条件
iodine
1.) THF, a) RT, 24 h, b) reflux, 3 h, 2.) THF; Yield given. Multistep reaction;
参考文献
Saednya, Akbar; Hart, Harold
Synthesis, 1996 , # 12 p. 1455 - 1458
反应条件
copper
T=180 - 220°C; 3 h;
参考文献
Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581
反应条件
copper
T=260 - 270°C; 3 h; Further byproducts given;
参考文献
Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581
反应条件
bis(acetylacetonate)nickel(II)
1.) reflux, 3h; 2.) hydrochloric acid; Yield given. Multistep reaction;
参考文献
Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581
反应条件
copper
T=260 - 270°C; 3 h;
参考文献
Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581
