1,2,3,4,6-alpha-D-葡萄糖五乙酸酯合成路线 （共 153 条）
反应条件
1: 30 percent / ZnCl2 / 9 h / 50 - 70 Torr / Heating 2: 55 percent / 0.01 N methanolic MeONa / 2 h / Heating View Scheme
参考文献
Helferich; Winkler
Chemische Berichte, 1933 , vol. 66, p. 1556
反应条件
1: pyridine; hydrogen fluoride / 4 h / 20 °C / Sealed vial 2: methanol; sodium methylate / 2 h / 0 °C / pH 8.5 View Scheme
参考文献
Wei, Jinhua; Lv, Xun; Lue, Yang; Yang, Gangzhu; Fu, Lifeng; Yang, Liu; Wang, Jianjun; Gao, Jianhui; Cheng, Shuihong; Duan, Qian; Jin, Cheng; Li, Xuebing
European Journal of Organic Chemistry, 2013 , # 12 p. 2414 - 2419
反应条件
1: 2,3,4,6-tetra-OAc-D-manopyranose; propargyl alcohol With copper(II) bis(trifluoromethanesulfonate) in acetonitrile T=20°C; 2 h; 2: D-galactal With trimethylsilylazide; copper in acetonitrile T=20°C; 9 h; optical yield given as percent dediastereoselective reaction;
参考文献
Yousuf, Syed Khalid; Taneja, Subhash Chandra; Mukherjee, Debaraj
Journal of Organic Chemistry, 2010 , vol. 75, # 9 p. 3097 - 3100
反应条件
1: 85 percent / BnNH2 / tetrahydrofuran / Ambient temperature 2: 97 percent / 1,2,4-triazole / CH2Cl2 / 2 h / Ambient temperature 3: 98 percent / 30percent H2O2 / tetrahydrofuran / 1.5 h / Ambient temperature 4: H2, 10percent NaHCO3 / 5percent Pd/C / ethanol / 10 h / 760.2 Torr / Ambient temperature 5: 1N NaOH / 3 h / Ambient temperature View Scheme
参考文献
Sim, Mui Mui; Kondo, Hirosato; Wong, Chi-Huey
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2260 - 2267
反应条件
iron(III) chloride in dichloromethane 1.) 5 min, 2.) r.t.; Yield given. Yields of byproduct given;
参考文献
Chatterjee, Swapan K.; Nuhn, Peter
Chemical Communications, 1998 , # 16 p. 1729 - 1730
反应条件
1: hydrogen bromide; acetic acid / 12 h / 20 °C / Inert atmosphere 2: acetic acid; zinc / water / -20 - 0 °C / Inert atmosphere 3: methanol; sodium methylate / 20 °C / Inert atmosphere 4: sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide; mineral oil / 4 h / 0 - 60 °C / Inert atmosphere View Scheme
参考文献
Vedachalam, Seenuvasan; Tan, Shi Min; Teo, Hui Ping; Cai, Shuting; Liu, Xue-Wei
Organic Letters, 2012 , vol. 14, # 1 p. 174 - 177
反应条件
1.1: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C / Inert atmosphere 2.1: methanol; sodium methylate / 20 °C 2.2: Amberlite.(R). IR-120 H+ ion exchange 3.1: sodium hydride / N,N-dimethyl-formamide / 2.5 h / 0 - 20 °C / Inert atmosphere 3.2: 12 h / 20 °C / Inert atmosphere 4.1: N-bromosuccinmide; water / acetone / 3 h / 20 °C View Scheme
参考文献
Lambu, Mallikharjuna Rao; Hussain, Altaf; Sharma, Deepak K.; Yousuf, Syed Khalid; Singh, Baldev; Tripathi, Anil. K.; Mukherjee, Debaraj
RSC Advances, 2014 , vol. 4, # 22 p. 11023 - 11028
反应条件
1: ZnCl2 3: acetonitrile / 4 h / 30 °C / anodic oxidation (Pt electrode, LiClO4 as electrolyte) View Scheme
参考文献
Balavoine, Gilbert; Gref, Aurore; Fischer, Jean-Claude; Lubineau, Andre
Tetrahedron Letters, 1990 , vol. 31, # 40 p. 5761 - 5764
反应条件
pyridine; hydrogen fluoride T=20°C; 4 h; Sealed vial;
参考文献
Steinmann, Andreas; Thimm, Julian; Matwiejuk, Martin; Thiem, Joachim
Macromolecules, 2010 , vol. 43, # 8 p. 3606 - 3612
反应条件
1: pyridine; hydrogen fluoride / -20 - 20 °C 2: methanol; sodium methylate / 20 °C 3: sodium hydroxide; Thermus nonproteolyticus HG102 E338A mutant; glycine / aq. buffer / 48 h / 45 °C / pH 8.8 / |Enzymatic reaction View Scheme
参考文献
Wei, Jinhua; Lv, Xun; Lue, Yang; Yang, Gangzhu; Fu, Lifeng; Yang, Liu; Wang, Jianjun; Gao, Jianhui; Cheng, Shuihong; Duan, Qian; Jin, Cheng; Li, Xuebing
European Journal of Organic Chemistry, 2013 , # 12 p. 2414 - 2419
