in water; acetonitrile
T=25°C; nucleophilic substitution reactions of p-nitrophenyl acetate with normal nucleophile and α-nucleophiles; various MeCN-H2O compositions; relative reactivity of the nucleophiles; solvent effect on reactivity, basicity; effect of solvent on α-effect; Rate constantProduct distribution;
sodium perchlorate in water
T=25.05°C; Deacetylation; pH=6.08 - 10.03; Kinetics;
参考文献
Redman, Kahlee; May, Bruce L.; Kean, Suzanna D.; Clements, Philip; Easton, Christopher J.; Lincoln, Stephen F.
Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 8 p. 1711 - 1717