1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux View Scheme

1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux View Scheme

1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux View Scheme

1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux View Scheme

1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux 13.1: iodine; potassium hydroxide / -5 - 0 °C 14.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 15.1: methanol; water; sodium hydroxide / 5 h / Reflux 15.2: 1 h / Reflux View Scheme

hydrogen; lithium iodide; nickel 1.) 140 deg C, 4 h, 2.) ethanol, 20 deg C, 1 atm, 30 h; Yield given. Multistep reaction;

T=640 - 670°C; P=0.75006 - 3.00024 Torr;

1: 85 percent / HBF4 / diethyl ether / 0.17 h / 105 - 110 °C 2: 1) 36percent H2O2, 2) 20percent KOH / 1) CHCl3, acetic acid, 45 deg C - 50 deg C, 1 h, 2) dioxane, reflux, 0.5 h View Scheme

1: 95 percent / HBF4 / diethyl ether / 0.17 h / 105 - 110 °C 2: 1) 36percent H2O2, 2) 20percent KOH / 1) CHCl3, acetic acid, 45 deg C - 50 deg C, 1 h, 2) dioxane, reflux, 0.5 h View Scheme

1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 2.1: methanol; water; sodium hydroxide / 5 h / Reflux 2.2: 1 h / Reflux View Scheme