2,4,6-三甲氧基苯甲醛合成路线 （共 65 条）
反应条件
1: AlBr3 / acetonitrile / 5 h / 20 °C
2: (C2H5)3SiH / trifluoroacetic acid / 20 °C
View Scheme
参考文献
Redda, Kinfe; Mills, Chavonda Janeebra; Maleeva, Nelly
Patent: US2012/264820 A1, 2012 ;
反应条件
1: 50 percent / 3-chloroperoxybenzoic acid / CH2Cl2 / 3 h / 20 °C
2: 41 percent / CuO / various solvent(s) / 63 h / Heating
3: 58 percent / boron tribromide / CH2Cl2 / 1 h / -80 °C
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参考文献
Paizs, Csaba; Bartlewski-Hof, Ulrike; Retey, Janos
Chemistry - A European Journal, 2007 , vol. 13, # 10 p. 2805 - 2811
反应条件
hydroxylamine hydrochloride; potassium carbonate in methanol
T=20°C;
参考文献
Hou, Yingwei; Lu, Shichao; Liu, Gang
Journal of Organic Chemistry, 2013 , vol. 78, # 17 p. 8386 - 8395
反应条件
1.1: boron tribromide / dichloromethane / -78 - 20 °C
1.2: Cooling with ice
2.1: potassium carbonate / N,N-dimethyl-formamide / 8 h / 80 °C
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 20 °C
4.1: sodium hydroxide / methanol / 3 h / 20 °C
5.1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 80 °C
6.1: trichlorophosphate / 3.5 h / 0 - 80 °C
View Scheme
参考文献
Huang, Guan-Jhong; Bhaskar Reddy, M. Vijaya; Kuo, Ping-Chung; Huang, Chieh-Hung; Shih, Hung-Cheng; Lee, E.-Jian; Yang, Mei-Lin; Leu, Yann-Lii; Wu, Tian-Shung
European Journal of Medicinal Chemistry, 2012 , vol. 48, p. 371 - 378
反应条件
T=80°C; Rate constant;
参考文献
Burkett et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 3923,3925
