in N,N-dimethyl-formamide T=0°C; nitrogen (leaving group) kinetic isotope effect for the SN2 reactions between p-substituted sodium thiophenoxides and benzyldimethylammonium nitrate; effect of ionic strength; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 119, # 16 p. 3670 - 3676
1: copper diacetate / N,N-dimethyl-formamide / 60 h / 130 °C / under air 2: copper diacetate / N,N-dimethyl-formamide / 30 h / 130 °C / under air View Scheme
参考文献
Chemical Communications, , vol. 47, # 26 p. 7380 - 7382
1.1: sodium hydroxide / water / 1 h / 20 °C 1.2: polyethylene glycol / 15 h / 110 °C 2.1: potassium hydroxide / water / 4 h / 110 °C 2.2: 1 h / 20 °C View Scheme
