(2,4,6-三-叔-丁基苯基)膦合成路线 （共 39 条）
反应条件
toluene-4-sulfonic acid in benzene 8 h; Heating; Title compound not separated from byproducts;
参考文献
Romanenko, V. D.; Ruban, A. V.; Chernega, A. N.; Povolotskii, M. I.; Antipin, M. Yu.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 8.1 p. 1718 - 1725,1528 - 1534
反应条件
1: lithiation View Scheme
参考文献
Yoshifuji, Masaaki; Toyota, Kozo; Inamoto, Naoki
Tetrahedron Letters, 1985 , vol. 26, # 14 p. 1727 - 1730
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Cowley, A. H.; Kilduff, J. E.; Newman, T. H.; Pakulski, M.
Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5820 - 5821
反应条件
lithium aluminium tetrahydride; chloro-trimethyl-silane in 1,4-dioxane
T=100°C; 5 h; Inert atmosphere;
参考文献
Fleming, Conor G. E.; Slawin, Alexandra M. Z.; Athukorala Arachchige, Kasun S.; Randall, Rebecca; Buehl, Michael; Kilian, Petr
Dalton Transactions, 2013 , vol. 42, # 5 p. 1437 - 1450
反应条件
GeI2 in benzene
T=60°C; 10 h;
参考文献
Veith, Michael; Huch, Volker; Majoral, Jean-Pierre; Bertrand, Guy; Manuel, Georges
Tetrahedron Letters, 1983 , vol. 24, # 39 p. 4219 - 4222
反应条件
water; 3-chloro-benzenecarboperoxoic acid in dichloromethane
T=0°C;
参考文献
Yoshifuji, Masaaki; Ando, Kaori; Toyota, Kozo; Shima, Ichiro; Inamoto, Naoki
Journal of the Chemical Society, Chemical Communications, 1983 , # 8 p. 419 - 420
反应条件
in toluene
refluxing for 12 h; removal of solvent and volatiles under vacuum, sublimation of the residue, crystals of the phosphine were formed, the Ga-compd. remained unsublimed, purification of Ga-compd. by recrystn. from toluene at -20°C;
参考文献
Atwood, D. A.; Cowly, A. H.; Jones, R. A.; Mardones, M. A.
Journal of the American Chemical Society, 1991 , vol. 113, p. 7050 - 7052
反应条件
water in dichloromethane
T=0°C;
参考文献
Yoshifuji, Masaaki; Ando, Kaori; Toyota, Kozo; Shima, Ichiro; Inamoto, Naoki
Journal of the Chemical Society, Chemical Communications, 1983 , # 8 p. 419 - 420
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
Cooling with iceRefluxInert atmosphere; SolventTimeReagent/catalyst;
参考文献
Fleming, Conor G. E.; Slawin, Alexandra M. Z.; Athukorala Arachchige, Kasun S.; Randall, Rebecca; Buehl, Michael; Kilian, Petr
Dalton Transactions, 2013 , vol. 42, # 5 p. 1437 - 1450
反应条件
lithium aluminium tetrahydride; cerium(III) chloride in 1,4-dioxane
T=101°C; 6 h; Inert atmosphere;
参考文献
Fleming, Conor G. E.; Slawin, Alexandra M. Z.; Athukorala Arachchige, Kasun S.; Randall, Rebecca; Buehl, Michael; Kilian, Petr
Dalton Transactions, 2013 , vol. 42, # 5 p. 1437 - 1450
