(2,4,6-三-叔-丁基苯基)膦合成路线 （共 39 条）
反应条件
tetrafluoroboric acid diethyl ether complex; methyllithium
1) THF, -78 deg C; 2) THF; Multistep reaction;
参考文献
Cowley, A. H.; Pakulski, M. K.
Journal of the American Chemical Society, 1984 , vol. 106, # 5 p. 1491 - 1492
反应条件
tetrafluoroboric acid diethyl ether complex
1) THF, -78 deg C; 2) THF,; Multistep reaction;
参考文献
Cowley, A. H.; Pakulski, M. K.
Journal of the American Chemical Society, 1984 , vol. 106, # 5 p. 1491 - 1492
反应条件
in tetrahydrofuran; benzene
T=120°C;
参考文献
Bertrand, Guy; Couret, Claude; Escudie, Jean; Majid, Samia; Majoral, Jean-Pierre
Tetrahedron Letters, 1982 , vol. 23, # 35 p. 3567 - 3570
反应条件
48 h; Ambient temperature;
参考文献
Cowley, A. H.; Kilduff, J. E.; Pakulski, M.; Stewart, C.A.
Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1655 - 1656
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / |Inert atmosphere
1.2: -78 - 20 °C
2.1: cerium(III) chloride; lithium aluminium tetrahydride / 1,4-dioxane / 6 h / 101 °C / |Inert atmosphere
View Scheme
参考文献
Fleming, Conor G. E.; Slawin, Alexandra M. Z.; Athukorala Arachchige, Kasun S.; Randall, Rebecca; Buehl, Michael; Kilian, Petr
Dalton Transactions, 2013 , vol. 42, # 5 p. 1437 - 1450
反应条件
tetrafluoroboric acid diethyl ether complex in tetrahydrofuran; diethyl ether
参考文献
Cowley, Alan H.; Kilduff, Jan E.; Norman, Nicholas C.; Pakulski, Marek
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1986 , p. 1801 - 1808
反应条件
ethylmagnesium bromide in tetrahydrofuran
1.) reflux, 30 min, 2.) r.t., 12 h;
参考文献
Maerkl, Gottfried; Hennig, Ruediger; Noeth, Heinrich
Liebigs Annalen, 1997 , # 1 p. 121 - 126
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / |Inert atmosphere
1.2: -78 - 20 °C
2.1: chloro-trimethyl-silane; lithium aluminium tetrahydride / 1,4-dioxane / 5 h / 100 °C / |Inert atmosphere
View Scheme
参考文献
Fleming, Conor G. E.; Slawin, Alexandra M. Z.; Athukorala Arachchige, Kasun S.; Randall, Rebecca; Buehl, Michael; Kilian, Petr
Dalton Transactions, 2013 , vol. 42, # 5 p. 1437 - 1450
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / |Inert atmosphere
1.2: -78 - 20 °C
2.1: lithium aluminium tetrahydride / tetrahydrofuran / |Cooling with ice; |Reflux; |Inert atmosphere
View Scheme
参考文献
Fleming, Conor G. E.; Slawin, Alexandra M. Z.; Athukorala Arachchige, Kasun S.; Randall, Rebecca; Buehl, Michael; Kilian, Petr
Dalton Transactions, 2013 , vol. 42, # 5 p. 1437 - 1450
参考文献
Yoshifuji, Masaaki; Ando, Kaori; Toyota, Kozo; Shima, Ichiro; Inamoto, Naoki
Journal of the Chemical Society, Chemical Communications, 1983 , # 8 p. 419 - 420
