(2,4,6-三-叔-丁基苯基)膦合成路线 （共 39 条）
反应条件
soufre in toluene
T=100°C; 5 h;
参考文献
Navech, Jaques; Revel, Monique; Kraemer, Raymond
Phosphorus and Sulfur and the Related Elements, 1984 , vol. 21, p. 105 - 110
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / Inert atmosphere
1.2: 0.25 h / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
View Scheme
参考文献
Sasaki, Shigeru; Yoshifuji, Masaaki; Inamoto, Naoki
Arkivoc, 2012 , vol. 2012, # 2 p. 15 - 23
反应条件
1: S8 / 100 °C
2: Ph3P
3: Ph3P
4: S8 / toluene / Heating
View Scheme
参考文献
Navech, J.; Revel, M.; Kraemer, R.
Tetrahedron Letters, 1985 , vol. 26, # 2 p. 207 - 210
反应条件
n-butyllithium
1.) hexane, THF, -78 deg C, 1 h, 2.) -78 deg C, 0.5 h; Yield given. Multistep reaction;
参考文献
Kawanami, Hajime; Toyota, Kozo; Yoshifuji, Masaaki
Journal of Organometallic Chemistry, 1997 , vol. 535, # 1-2 p. 1 - 5
反应条件
1: 1.) butyllithium / 1.) THF, -78 deg C, 2.) room temperature
2: 1.) butyllithium / 1.) room temperature, 2.) -78 deg C
View Scheme
参考文献
Yoshifuji, Masaaki; Toyota, Kozo; Shibayama, Katsuhiro; Inamoto, Naoki
Tetrahedron Letters, 1984 , vol. 25, # 17 p. 1809 - 1812
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Niitsu, Takashi; Inamoto, Naoki; Toyota, Kozo; Yoshifuji, Masaaki
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 9 p. 2736 - 2738
反应条件
potassium hydroxide in tetrahydrofuran
24 h; Yield given;
参考文献
Appel, Rolf; Casser, Carl; Immenkeppel, Michael; Knoch, Falk
Angewandte Chemie, 1984 , vol. 96, # 11 p. 905 - 906
反应条件
in benzene
24 h; Ambient temperature;
参考文献
Navech, J.; Germa, H.; Mathieu, S.
Phosphorus and Sulfur and the Related Elements, 1988 , vol. 35, p. 247 - 260
反应条件
in benzene
24 h; Ambient temperaturefurther solvent; MechanismProduct distribution;
参考文献
Navech, J.; Germa, H.; Mathieu, S.
Phosphorus and Sulfur and the Related Elements, 1988 , vol. 35, p. 247 - 260
