10B-三甲基硅烷基氧基-2,3-二氢荧-1-酮合成路线 （共 7 条）
反应条件
1,1,1,3,3,3-hexamethyl-disilazane in pyridine
0.75 h; Ambient temperature;
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 87 percent / OsO4, N-methylmorpholine N-oxide dihydrate / tetrahydrofuran; H2O / 144 h / Ambient temperature
2: 97 percent / CH3SO3H / CH2Cl2
3: 96 percent / hexamethyldisilazane / CH2Cl2 / Ambient temperature
4: 61 percent / 99percent m-chloroperoxybenzoic acid / CH2Cl2 / 0.58 h / 0 °C
5: 92 percent / hexamethyldisilazane / pyridine / 0.75 h / Ambient temperature
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: CH3SO3H / CH2Cl2
2: 87 percent / OsO4, N-methylmorpholine N-oxide dihydrate / tetrahydrofuran; H2O / 144 h / Ambient temperature
3: 97 percent / CH3SO3H / CH2Cl2
4: 96 percent / hexamethyldisilazane / CH2Cl2 / Ambient temperature
5: 61 percent / 99percent m-chloroperoxybenzoic acid / CH2Cl2 / 0.58 h / 0 °C
6: 92 percent / hexamethyldisilazane / pyridine / 0.75 h / Ambient temperature
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: O2, KOH, 18-crown-6 / benzene / 24 h
2: CH3SO3H / CH2Cl2
3: 87 percent / OsO4, N-methylmorpholine N-oxide dihydrate / tetrahydrofuran; H2O / 144 h / Ambient temperature
4: 97 percent / CH3SO3H / CH2Cl2
5: 96 percent / hexamethyldisilazane / CH2Cl2 / Ambient temperature
6: 61 percent / 99percent m-chloroperoxybenzoic acid / CH2Cl2 / 0.58 h / 0 °C
7: 92 percent / hexamethyldisilazane / pyridine / 0.75 h / Ambient temperature
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 96 percent / hexamethyldisilazane / CH2Cl2 / Ambient temperature
2: 61 percent / 99percent m-chloroperoxybenzoic acid / CH2Cl2 / 0.58 h / 0 °C
3: 92 percent / hexamethyldisilazane / pyridine / 0.75 h / Ambient temperature
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 97 percent / CH3SO3H / CH2Cl2
2: 96 percent / hexamethyldisilazane / CH2Cl2 / Ambient temperature
3: 61 percent / 99percent m-chloroperoxybenzoic acid / CH2Cl2 / 0.58 h / 0 °C
4: 92 percent / hexamethyldisilazane / pyridine / 0.75 h / Ambient temperature
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 61 percent / 99percent m-chloroperoxybenzoic acid / CH2Cl2 / 0.58 h / 0 °C
2: 92 percent / hexamethyldisilazane / pyridine / 0.75 h / Ambient temperature
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
