10,11-二氢-5H-二苯并[a,d]环庚烯合成路线 （共 47 条）
反应条件
1: 550 °C / 3 Torr 2: AlCl3 / benzene; nitromethane View Scheme
参考文献
Synthesis, , p. 214 - 215
反应条件
1: N-bromosuccinimide, benzoyl peroxide / CCl4 / 12 h / Heating 2: methylmagnesium iodide / diethyl ether / 2 h / Heating 3: 1.) n-BuLi / 1.) Et2O, hexane, RT, 30 min, 2.) Et2O, hexane 4: 79 percent / NaBH4 / methanol / 12 h / Heating 5: 40 percent / benzene / 2 h / Heating View Scheme
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 1708 - 1735
反应条件
1: 1.) n-BuLi / 1.) Et2O, hexane, RT, 30 min, 2.) Et2O, hexane 2: 79 percent / NaBH4 / methanol / 12 h / Heating 3: 40 percent / benzene / 2 h / Heating View Scheme
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 1708 - 1735
反应条件
1: 79 percent / NaBH4 / methanol / 12 h / Heating 2: 40 percent / benzene / 2 h / Heating View Scheme
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 1708 - 1735
反应条件
1: methylmagnesium iodide / diethyl ether / 2 h / Heating 2: 1.) n-BuLi / 1.) Et2O, hexane, RT, 30 min, 2.) Et2O, hexane 3: 79 percent / NaBH4 / methanol / 12 h / Heating 4: 40 percent / benzene / 2 h / Heating View Scheme
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 1708 - 1735
反应条件
1: Zn / 290 °C 2: aq. HCl / ethanol 3: NaOMe, Py 4: but-2c-ene / Irradiation View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 40, p. 1506 - 1511
反应条件
1: thiourea / benzene 2: Zn / 290 °C 3: aq. HCl / ethanol 4: NaOMe, Py 5: but-2c-ene / Irradiation View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 40, p. 1506 - 1511
反应条件
in neat (no solvent) T=400°C; P=15 Torr; 24 h; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 45, # 1 p. 143 - 149
反应条件
benzene 2 h; Heating;
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 1708 - 1735
反应条件
1: sodium tetrahydroborate; sodium hydroxide / methanol 2: quartz / 350 - 650 °C / Inert atmosphere; Pyrolysis 3: sodium tetrahydroborate; sodium hydroxide / methanol 4: H-ZSM-5 β mesoporous zeolite / 300 °C / Inert atmosphere; Pyrolysis View Scheme
参考文献
Revue Roumaine de Chimie, , vol. 55, # 10 p. 711 - 714
