1: 1-(phenylthio)pentan-2-one With sodium hydride in tetrahydrofuran
T=20°C;
2: (Z)-3-methylhex-2-enyl bromide in tetrahydrofuran
T=20°C;
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.75 h / 0 °C
1.2: 7 percent / tetrahydrofuran; hexane / 0 - 20 °C
2.1: sodium hydride / tetrahydrofuran / 20 °C
2.2: 60 percent / tetrahydrofuran / 20 °C
View Scheme
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
1.1: phosphorus tribromide; pyridine / diethyl ether; hexane / 4 h / -15 - -10 °C
2.1: sodium hydride / tetrahydrofuran / 20 °C
2.2: 60 percent / tetrahydrofuran / 20 °C
View Scheme
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
1.1: lithium diethylamide / tetrahydrofuran; hexane / -10 - 0 °C
1.2: tetrahydrofuran; hexane; hexamethylphosphoric acid triamide / -70 - 0 °C
1.3: 61 percent / hydrochloric acid / tetrahydrofuran; hexane; hexamethylphosphoric acid triamide / 3.5 h / 20 °C
2.1: 94 percent / sodium borohydride
3.1: pyridine-sulfur trioxide / tetrahydrofuran / 3 h / 0 °C
3.2: 67 percent / LiAlH4 / tetrahydrofuran / 25 h
4.1: lithium; liquid ammonia / 3 h / -40 °C
5.1: phosphorus tribromide; pyridine / diethyl ether; hexane / 4 h / -15 - -10 °C
6.1: sodium hydride / tetrahydrofuran / 20 °C
6.2: 60 percent / tetrahydrofuran / 20 °C
View Scheme
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
1.1: 94 percent / sodium borohydride
2.1: pyridine-sulfur trioxide / tetrahydrofuran / 3 h / 0 °C
2.2: 67 percent / LiAlH4 / tetrahydrofuran / 25 h
3.1: lithium; liquid ammonia / 3 h / -40 °C
4.1: phosphorus tribromide; pyridine / diethyl ether; hexane / 4 h / -15 - -10 °C
5.1: sodium hydride / tetrahydrofuran / 20 °C
5.2: 60 percent / tetrahydrofuran / 20 °C
View Scheme
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
1.1: lithium; liquid ammonia / 3 h / -40 °C
2.1: phosphorus tribromide; pyridine / diethyl ether; hexane / 4 h / -15 - -10 °C
3.1: sodium hydride / tetrahydrofuran / 20 °C
3.2: 60 percent / tetrahydrofuran / 20 °C
View Scheme
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
1.1: pyridine-sulfur trioxide / tetrahydrofuran / 3 h / 0 °C
1.2: 67 percent / LiAlH4 / tetrahydrofuran / 25 h
2.1: lithium; liquid ammonia / 3 h / -40 °C
3.1: phosphorus tribromide; pyridine / diethyl ether; hexane / 4 h / -15 - -10 °C
4.1: sodium hydride / tetrahydrofuran / 20 °C
4.2: 60 percent / tetrahydrofuran / 20 °C
View Scheme
参考文献
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
Grigorieva, N. Ya.; Tsiklauri, P. G.
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 665 - 670
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2004 , # 3 p. 635 - 639
