(1aR,9-alpha,10-beta,10a-alpha)-10,10a-二氢-9H-荧并(1,10b-beta)环氧乙烯-9,10-二醇合成路线 （共 7 条）
反应条件
3-chloro-benzenecarboperoxoic acid in chloroform
T=0°C; 1 h;
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 21 percent / NaBH4, O2 / ethanol / 48 h
2: 55 percent / m-chloroperbenzoic acid / tetrahydrofuran / 3 h
View Scheme
参考文献
Balanikas, George; Hussain, Nalband; Amin, Shantu; Hecht, Stephen S.
Journal of Organic Chemistry, 1988 , vol. 53, # 5 p. 1007 - 1010
反应条件
1: 84 percent / NaBH4 / methanol / 0 °C
2: 100 percent / p-toluenesulfonic acid / benzene / 2 h / Heating
3: 1.) I2 / 1.) C6H6, 2.) overnight
4: 48 percent / o-chloranil / dioxane / Heating; overnight
5: 83 percent / 1 N NaOMe / tetrahydrofuran; methanol / 1 h / -20 °C
6: 66 percent / 99percent m-chloroperoxybenzoic acid / CHCl3 / 1 h / 0 °C
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 1.) I2 / 1.) C6H6, 2.) overnight
2: 48 percent / o-chloranil / dioxane / Heating; overnight
3: 83 percent / 1 N NaOMe / tetrahydrofuran; methanol / 1 h / -20 °C
4: 66 percent / 99percent m-chloroperoxybenzoic acid / CHCl3 / 1 h / 0 °C
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 100 percent / p-toluenesulfonic acid / benzene / 2 h / Heating
2: 1.) I2 / 1.) C6H6, 2.) overnight
3: 48 percent / o-chloranil / dioxane / Heating; overnight
4: 83 percent / 1 N NaOMe / tetrahydrofuran; methanol / 1 h / -20 °C
5: 66 percent / 99percent m-chloroperoxybenzoic acid / CHCl3 / 1 h / 0 °C
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 83 percent / 1 N NaOMe / tetrahydrofuran; methanol / 1 h / -20 °C
2: 66 percent / 99percent m-chloroperoxybenzoic acid / CHCl3 / 1 h / 0 °C
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
反应条件
1: 48 percent / o-chloranil / dioxane / Heating; overnight
2: 83 percent / 1 N NaOMe / tetrahydrofuran; methanol / 1 h / -20 °C
3: 66 percent / 99percent m-chloroperoxybenzoic acid / CHCl3 / 1 h / 0 °C
View Scheme
参考文献
Rastetter, William H.; Nachbar, Robert B.; Russo-Rodriguez, Sandra; Wattley, Ruth V.; Thilly, William G.; et al.
Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4873 - 4878
