4 -甲氧基二苯基甲烷合成路线 （共 196 条）
反应条件
1: 92 percent / tetrahydrofuran; diethyl ether / 6 h / Heating
2: 94 percent / aq. ethanol; Raney Nickel / 5 h / Heating
View Scheme
参考文献
Khim, Seock-Kyu; Dai, Mingshi; Zhang, Xuqing; Chen, Lei; Pettus, Liping; Thakkar, Kshitij; Schultz, Arthur G.
Journal of Organic Chemistry, 2004 , vol. 69, # 22 p. 7728 - 7733
反应条件
1: 1-bromo-4-methoxy-benzene With magnesium in tetrahydrofuran
2: With zinc dibromide in tetrahydrofuran
3: benzyl chloride With cobalt(II) dibromide in tetrahydrofuran
参考文献
Amatore, Muriel; Gosmini, Corinne
Chemical Communications, 2008 , # 40 p. 5019 - 5021
反应条件
C30H21F6N2NiO2P in tetrahydrofuran
T=70°C; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Someya, Chika I.; Weidauer, Maik; Enthaler, Stephan
Catalysis Letters, 2013 , vol. 143, # 5 p. 424 - 431
反应条件
Pd0(tris(tert-butyl)phosphine)2; potassium tetrakis(pentafluorophenyl)-borate in toluene
T=23°C; 16 h; Inert atmosphere;
参考文献
Durak, Landon J.; Lewis, Jared C.
Organometallics, 2014 , vol. 33, # 3 p. 620 - 623
反应条件
digallium tetrachloride in carbon disulfide
24 h; Ambient temperatureother aromatic aldehydes or carbonyl compounds, other solvent, other temp.; Product distribution;
参考文献
Hashimoto; Hirata; Kihara; Hasegawa; Saigo
Tetrahedron Letters, 1992 , vol. 33, # 42 p. 6351 - 6354
反应条件
boron trifluoride in neat (no solvent)
T=25°C; 0.00138889 h; Product distribution;
参考文献
Olah, George A.; Olah, Judith A.; Ohyama, Toshiyuki
Journal of the American Chemical Society, 1984 , vol. 106, # 18 p. 5284 - 5290
反应条件
boron trifluoride in neat (no solvent)
T=0°C; 0.166667 h; Product distribution;
参考文献
Olah, George A.; Olah, Judith A.; Ohyama, Toshiyuki
Journal of the American Chemical Society, 1984 , vol. 106, # 18 p. 5284 - 5290
反应条件
titanium tetrachloride in nitromethane
T=25°C; kinetics, oth. temp., oth. solvents, Ea, ΔH(excit.), ΔG(excit.), ΔS(excit.); Rate constantProduct distributionThermodynamic data;
参考文献
DeHaan, Franklin P.; Chan, Wai H.; Chang, Jeffrey; Cheng, Terry B.; Chiriboga, Douglas A.; Irving, Mark M.; Kaufman, Craig R.; Kim, Gia Y.; Kumar, Amit; Na, Jim; Nguyen, Tien T.; Tim Nguyen; Patel, Bimal R.; Sarin, Neal P.; Tidwell, Jeffrey H.
Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 356 - 363
反应条件
1.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h
1.2: 2 h
2.1: copper(l) iodide / tetrahydrofuran / 2 h / 70 °C / Inert atmosphere
View Scheme
参考文献
Li, Man-Bo; Tang, Xiang-Ling; Tian, Shi-Kai
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1980 - 1984
反应条件
1.1: triethylamine / N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere
2.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h
2.2: 2 h
3.1: copper(l) iodide / tetrahydrofuran / 2 h / 70 °C / Inert atmosphere
View Scheme
参考文献
Li, Man-Bo; Tang, Xiang-Ling; Tian, Shi-Kai
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1980 - 1984
