反式-1-辛烯-1-基硼酸频哪酯合成路线 （共 14 条）
反应条件
1: 2,3-dimethylbutane-2,3-diol With dimethylsulfide borane complex in diethyl ether; dichloromethane T=0 - 20°C; 3 h; 2: anhydrous 1-octyne in diethyl ether; dichloromethane T=20°C; 12 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 353, # 11-12 p. 2169 - 2173
反应条件
1: anhydrous 1-octyne With [RhCl(η2:η2-cycloocta-1,5-diene)]2; triethylamine; benzo[1,3,2]dioxaborole in cyclohexane T=20°C; hydroboration; 1 h; 2: 2,3-dimethylbutane-2,3-diol in cyclohexane Substitution;
参考文献
Journal of the American Chemical Society, , vol. 122, # 20 p. 4990 - 4991
反应条件
1: anhydrous 1-octyne With [RhCl(η2:η2-cycloocta-1,5-diene)]2; triethylamine; benzo[1,3,2]dioxaborole in cyclohexane T=20°C; hydroboration; 1 h; 2: 2,3-dimethylbutane-2,3-diol in cyclohexane Substitution; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 122, # 20 p. 4990 - 4991
反应条件
bis(cyclohexanyl)borane T=20°C; 2 h;
参考文献
Synthesis, , # 11 p. 1814 - 1820
反应条件
sodium methylate; copper in ethanol T=25°C; 11 h; Schlenk techniqueInert atmosphereSealed tube; regioselective reaction;
参考文献
Chemical Communications, , vol. 50, # 16 p. 2058 - 2060
反应条件
triethylamine; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in tetrahydrofuran T=25°C; 14 h; Title compound not separated from byproducts.;
参考文献
Tetrahedron, , vol. 64, # 29 p. 6853 - 6862
反应条件
triphenylphosphine in toluene T=45°C; P=1125.11 Torr; 0.5 h; Inert atmosphere; stereoselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 8 p. 2467 - 2478
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; triethylamine in cyclohexane T=20°C; hydroboration; 1 h; Product distribution; Further Variations:Reagents;
参考文献
Journal of the American Chemical Society, , vol. 122, # 20 p. 4990 - 4991
反应条件
(CH3Si(C6H4P(C6H3(CF3)2)2)2)Pd(SO3CF3); triethylaluminum in tetrahydrofuran T=60°C; 6 h; Inert atmosphere; optical yield given as percent de;
参考文献
Journal of the American Chemical Society, , vol. 133, # 33 p. 12980 - 12983
反应条件
Grubb's 2nd generation catalyst in dichloromethane olefin cross-metathesis; 12 h; Heating; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 68, # 15 p. 6031 - 6034
