2,3-二氯-5,6-二氰基-1,4-苯醌合成路线 （共 141 条）
反应条件
copper diacetate; silver(l) oxide in 1-methyl-pyrrolidin-2-one T=120°C; 20 h;
参考文献
Zheng, Kui; Yu, Peng; Chen, Shuyou; Chen, Fen; Cheng, Jiang
Chinese Journal of Chemistry, 2013 , vol. 31, # 4 p. 449 - 452
反应条件
in acetonitrile stirring of a soln. of the compd. with DDQ in CH3CN (room temp., 30 min); filtration (sintered glass filter), evapn. to dryness, redissolving of the residue in CH2Cl2, chromy. (alumina column, CH2Cl2), removal of solvent;
参考文献
Lee, C. C.; Zhang, C. H.; Abd-El-Aziz, A. S.; Piorko, A.; Sutherland, R. G.
Journal of Organometallic Chemistry, 1989 , vol. 364, p. 217 - 230
反应条件
trimethylsilyl cyanide; lithium perchlorate in benzene T=25°C; 0.75 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Sundberg, Richard J.; Theret, Marie-Helene; Wright, Lorna
Organic Preparations and Procedures International, 1994 , vol. 26, # 3 p. 386 - 389
反应条件
Ag2CO3; copper(II) bis(trifluoromethanesulfonate); potassium carbonate in N,N-dimethyl-formamide T=100°C; 20 h; Reagent/catalystSolvent;
参考文献
Zhang, Guangyou; Chen, Shuyou; Fei, Haiyang; Cheng, Jiang; Chen, Fan
Synlett, 2012 , vol. 23, # 15 p. 2247 - 2250
反应条件
copper diacetate; silver(l) oxide in 1-methyl-pyrrolidin-2-one T=120°C; 20 h; Reagent/catalystSolvent;
参考文献
Zheng, Kui; Yu, Peng; Chen, Shuyou; Chen, Fen; Cheng, Jiang
Chinese Journal of Chemistry, 2013 , vol. 31, # 4 p. 449 - 452
反应条件
water in benzene 1 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 7 p. 2039 - 2044
反应条件
in acetonitrile
Yield given. Yields of byproduct given;
参考文献
Nishida, Shinya; Murakami, Masashi; Oda, Hirofumi; Tsuji, Takashi; Mizuno, Tetsuo; et al.
Journal of Organic Chemistry, 1989 , vol. 54, # 16 p. 3859 - 3868
反应条件
1: sodium metabisulfite, H2O / diethyl ether / 0.5 h
2: aq. KOH, tetrabutylammonium bromide / 18 h / 100 °C
View Scheme
参考文献
Cook, Michael J.; Dunn, Adrian J.; Howe, Steven D.; Thomson, Andrew J.; Harrison, Kenneth J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 2453 - 2458
反应条件
trimethylsilyl cyanide; lithium perchlorate in benzene-d6
T=25°C; 3 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Sundberg, Richard J.; Theret, Marie-Helene; Wright, Lorna
Organic Preparations and Procedures International, 1994 , vol. 26, # 3 p. 386 - 389
反应条件
10-methyl-9,10-dihydroacridine in acetonitrile
T=24.9°C; AcH2 as a simple acid-stable NADH model: the effect of HClO4 and Mg(ClO4)2 on rate constant of the hydrid transfer reaction is measured; Rate constant;
参考文献
Fukuzumi, Shunichi; Ishikawa, Masashi; Tanaka, Toshio
Tetrahedron, 1986 , vol. 42, # 4 p. 1021 - 1034
