4,4'-二溴-2,2'-联吡啶1,1'-二氧化物合成路线 （共 7 条）
反应条件
1.1: phosphorus tribromide / acetonitrile / 4 h / Reflux 2.1: sodium carbonate / water; toluene / 0.25 h / Inert atmosphere 2.2: 14 h / Reflux View Scheme
参考文献
Han, Won-Sik; Han, Jung-Kyu; Kim, Hyun-Young; Choi, Mi Jin; Kang, Yong-Soo; Pac, Chyongjin; Kang, Sang Ook
Inorganic Chemistry, 2011 , vol. 50, # 8 p. 3271 - 3280
反应条件
phosphorus tribromide in acetonitrile 4 h; Reflux;
参考文献
Inorganic Chemistry, , vol. 50, # 8 p. 3271 - 3280
反应条件
acetyl-bromide in acetic acid
T=100°C; 4 h;
参考文献
Han, Won-Sik; Han, Jung-Kyu; Kim, Hyun-Young; Choi, Mi Jin; Kang, Yong-Soo; Pac, Chyongjin; Kang, Sang Ook
Inorganic Chemistry, 2011 , vol. 50, # 8 p. 3271 - 3280
反应条件
1: 35percent H2O2; AcOH / 80 °C
2: 90percent HNO3; 30percent SO3 / H2SO4 / 110 °C
3: AcBr / acetic acid / Heating
View Scheme
参考文献
Carlson, Brenden; Phelan, Gregory D.; Kaminsky, Werner; Dalton, Larry; Jiang, Xuezhong; Liu, Sen; Jen, Alex K.-Y.
Journal of the American Chemical Society, 2002 , vol. 124, # 47 p. 14162 - 14172
反应条件
1: 90percent HNO3; 30percent SO3 / H2SO4 / 110 °C
2: AcBr / acetic acid / Heating
View Scheme
参考文献
Carlson, Brenden; Phelan, Gregory D.; Kaminsky, Werner; Dalton, Larry; Jiang, Xuezhong; Liu, Sen; Jen, Alex K.-Y.
Journal of the American Chemical Society, 2002 , vol. 124, # 47 p. 14162 - 14172
参考文献
Maerker; Case
Journal of the American Chemical Society, 1958 , vol. 80, p. 2745,2747
反应条件
1.1: PBr3 / CHCl3
2.1: tetrakis(triphenylphosphine) Pd(0); aq. potassium carbonate / dimethylformamide / 24 h / 85 - 95 °C
2.2: 30.4 percent / dimethylformamide / 5 h / 115 °C
View Scheme
参考文献
Carlson, Brenden; Phelan, Gregory D.; Kaminsky, Werner; Dalton, Larry; Jiang, Xuezhong; Liu, Sen; Jen, Alex K.-Y.
Journal of the American Chemical Society, 2002 , vol. 124, # 47 p. 14162 - 14172
