1,3,5-三氟-2,4,6-tri碘苯合成路线 （共 8 条）
反应条件
sulfuric acid; periodic acid; potassium iodide T=70°C; 4 h;
参考文献
European Journal of Organic Chemistry, , # 23 p. 3927 - 3935
反应条件
trifluorormethanesulfonic acid; SbF5; sodium iodide; Tl(OCOCF3)3 2.) 80 deg C, 3 h; Yield given. Multistep reaction;
参考文献
Australian Journal of Chemistry, , vol. 35, # 8 p. 1587 - 1597
反应条件
in various solvent(s) T=-265.66°C; Product distribution;
参考文献
European Journal of Organic Chemistry, , # 23 p. 3927 - 3935
反应条件
in various solvent(s) T=-265.66°C; Product distribution;
参考文献
European Journal of Organic Chemistry, , # 23 p. 3927 - 3935
反应条件
1: 1,3,5-triiodo-2,4,6-trifluorobenzene With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine T=20°C; Sonogashira coupling; 0.5 h; Inert atmosphere; 2: (thiophen-3-yl)acetylene T=70°C; Sonogashira coupling; 18 h; Inert atmosphere;
参考文献
Oliva, Maria Moreno; Casado, Juan; Navarrete, Juan T. Lopez; Hennrich, Gunther; Van Cleuvenbergen, Stijn; Asselberghs, Inge; Clays, Koen; Delgado, M. Carmen Ruiz; Bredas, Jean-Luc; De Melo, J. Sergio Seixas; De Cola, Luisa
Chemistry - A European Journal, 2009 , vol. 15, # 33 p. 8223 - 8234
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine
T=80°C; Sonogashira Cross-Coupling; 14 h;
参考文献
Tsuji, Hayato; Cantagrel, Guillaume; Ueda, Yasuyuki; Chen, Ting; Wan, Li-Jun; Nakamura, Eiichi
Chemistry - An Asian Journal, 2013 , vol. 8, # 10 p. 2377 - 2382
反应条件
in various solvent(s)
T=-270.16°C; 16 h; Irradiation;
参考文献
Wenk, Hans Henning; Sander, Wolfram
European Journal of Organic Chemistry, 2002 , # 23 p. 3927 - 3935
反应条件
1: Pyrolysis
2: Pyrolysis
View Scheme
参考文献
Venkataramani, Sugumar; Winkler, Michael; Sander, Wolfram
Angewandte Chemie - International Edition, 2007 , vol. 46, # 26 p. 4888 - 4893
