1.1: potassium carbonate; methanol / 3 h / 20 °C / |Inert atmosphere 2.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / |Inert atmosphere 3.1: 2-methyl-but-2-ene; sodium dihydrogen phosphate dihydrate; sodium chlorite / water; dichloromethane; tert-butyl alcohol / 18 h / 0 °C 4.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / 2 h / 20 °C / |Inert atmosphere 5.1: magnesium; methanol / 3 h / -20 °C / |Inert atmosphere 6.1: caesium carbonate / acetone / 13 h / 0 °C / |Inert atmosphere; |Darkness 7.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 8.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 9.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 9.2: 0.42 h / 0 °C / |Inert atmosphere 10.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 11.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 11.2: 10 h / 60 °C / |Inert atmosphere 12.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 13.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 14.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 14.2: -78 - -30 °C View Scheme

1.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / |Inert atmosphere 2.1: 2-methyl-but-2-ene; sodium dihydrogen phosphate dihydrate; sodium chlorite / water; dichloromethane; tert-butyl alcohol / 18 h / 0 °C 3.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / 2 h / 20 °C / |Inert atmosphere 4.1: magnesium; methanol / 3 h / -20 °C / |Inert atmosphere 5.1: caesium carbonate / acetone / 13 h / 0 °C / |Inert atmosphere; |Darkness 6.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 7.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 8.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 8.2: 0.42 h / 0 °C / |Inert atmosphere 9.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 10.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 10.2: 10 h / 60 °C / |Inert atmosphere 11.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 12.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 13.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 13.2: -78 - -30 °C View Scheme

1.1: magnesium; methanol / 3 h / -20 °C / |Inert atmosphere 2.1: caesium carbonate / acetone / 13 h / 0 °C / |Inert atmosphere; |Darkness 3.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 4.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 5.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 5.2: 0.42 h / 0 °C / |Inert atmosphere 6.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 7.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 7.2: 10 h / 60 °C / |Inert atmosphere 8.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 9.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 10.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 10.2: -78 - -30 °C View Scheme

1.1: caesium carbonate / acetone / 13 h / 0 °C / |Inert atmosphere; |Darkness 2.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 3.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 4.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 4.2: 0.42 h / 0 °C / |Inert atmosphere 5.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 6.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 6.2: 10 h / 60 °C / |Inert atmosphere 7.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 8.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 9.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 9.2: -78 - -30 °C View Scheme

1.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 2.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 3.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 3.2: 0.42 h / 0 °C / |Inert atmosphere 4.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 5.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 5.2: 10 h / 60 °C / |Inert atmosphere 6.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 7.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 8.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 8.2: -78 - -30 °C View Scheme

1.1: triethylamine; 4-(N,N-dimethlyamino)pyridine / dichloromethane / 12 h / 20 °C / |Inert atmosphere 2.1: triphenylphosphine; diethylazodicarboxylate; diphenyl phosphoryl azide / tetrahydrofuran; toluene / 5 h / 0 °C / |Inert atmosphere 3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 °C / |Inert atmosphere 4.1: potassium tert-butylate / tetrahydrofuran / 12.5 h / 20 °C / |Inert atmosphere; |Darkness 5.1: triethylamine; thiophenol; tin(ll) chloride / tetrahydrofuran / 1 h / 20 °C 6.1: triethylamine / dichloromethane / 18 h / 20 °C / |Inert atmosphere 7.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 8.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 9.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 9.2: 0.42 h / 0 °C / |Inert atmosphere 10.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 11.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 11.2: 10 h / 60 °C / |Inert atmosphere 12.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 13.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 14.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 14.2: -78 - -30 °C View Scheme

1.1: triphenylphosphine; diethylazodicarboxylate; diphenyl phosphoryl azide / tetrahydrofuran; toluene / 5 h / 0 °C / |Inert atmosphere 2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 °C / |Inert atmosphere 3.1: potassium tert-butylate / tetrahydrofuran / 12.5 h / 20 °C / |Inert atmosphere; |Darkness 4.1: triethylamine; thiophenol; tin(ll) chloride / tetrahydrofuran / 1 h / 20 °C 5.1: triethylamine / dichloromethane / 18 h / 20 °C / |Inert atmosphere 6.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 7.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 8.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 8.2: 0.42 h / 0 °C / |Inert atmosphere 9.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 10.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 10.2: 10 h / 60 °C / |Inert atmosphere 11.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 12.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 13.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 13.2: -78 - -30 °C View Scheme

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 °C / |Inert atmosphere 2.1: potassium tert-butylate / tetrahydrofuran / 12.5 h / 20 °C / |Inert atmosphere; |Darkness 3.1: triethylamine; thiophenol; tin(ll) chloride / tetrahydrofuran / 1 h / 20 °C 4.1: triethylamine / dichloromethane / 18 h / 20 °C / |Inert atmosphere 5.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 6.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 7.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 7.2: 0.42 h / 0 °C / |Inert atmosphere 8.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 9.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 9.2: 10 h / 60 °C / |Inert atmosphere 10.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 11.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 12.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 12.2: -78 - -30 °C View Scheme

1.1: potassium tert-butylate / tetrahydrofuran / 12.5 h / 20 °C / |Inert atmosphere; |Darkness 2.1: triethylamine; thiophenol; tin(ll) chloride / tetrahydrofuran / 1 h / 20 °C 3.1: triethylamine / dichloromethane / 18 h / 20 °C / |Inert atmosphere 4.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 5.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 6.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 6.2: 0.42 h / 0 °C / |Inert atmosphere 7.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 8.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 8.2: 10 h / 60 °C / |Inert atmosphere 9.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 10.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 11.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 11.2: -78 - -30 °C View Scheme

1.1: triethylamine; thiophenol; tin(ll) chloride / tetrahydrofuran / 1 h / 20 °C 2.1: triethylamine / dichloromethane / 18 h / 20 °C / |Inert atmosphere 3.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 4.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 5.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 5.2: 0.42 h / 0 °C / |Inert atmosphere 6.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 7.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 7.2: 10 h / 60 °C / |Inert atmosphere 8.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 9.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 10.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 10.2: -78 - -30 °C View Scheme