2-[(4-甲基苯基)亚甲基]庚烷-1-醛合成路线 (共 2 条)
反应条件
(E,Z)-crotononitrile; ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in neat (no solvent)
T=120°C; 3 h; Microwave irradiationInert atmosphereSealed tube; chemoselective reaction;
参考文献
Mura, Manuel G.; De Luca, Lidia; Taddei, Maurizio; Williams, Jonathan M. J.; Porcheddu, Andrea
Organic Letters, 2014 , vol. 16, # 10 p. 2586 - 2589
反应条件
trimethylsilyl trifluoromethanesulfonate in dichloromethane
T=0°C; 4 h;
参考文献
Duhamel, Lucette
Tetrahedron Letters, 1993 , vol. 34, # 48 p. 7745 - 7748