2,6-双(4,4,5,5-四甲基-1,3,2-二噁硼烷-2-基)蒽合成路线 （共 5 条）
反应条件
potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in 1,4-dioxane
T=110°C; 15 h; Inert atmosphere;
参考文献
SCHERING CORPORATION; ROSENBLUM, Stuart, B.; CHEN, Kevin, X.; KOZLOWSKI, Joseph, A.; NJOROGE, F., George; COBURN, Craig, A.
Patent: WO2010/132538 A1, 2010 ;
Location in patent: Page/Page column 110 ;
WO 2010/132538 A1
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; potassium acetate; palladium dichloride in dimethyl sulfoxide
T=60°C; 16 h;
参考文献
Stone, Matthew T.; Anderson, Harry L.
Chemical Communications, 2007 , # 23 p. 2387 - 2389
反应条件
potassium acetate in dimethyl sulfoxide
参考文献
Gilead Sciences, Inc.
Patent: US2011/306541 A1, 2011 ;
反应条件
4,4'-di-tert-butyl-2,2'-bipyridine; bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I) in cyclohexane
80°C, 18 h under Ar in the dark; 1:1 mixt. of 2,6- and 2,7- disubstituted compds. recrystd. (hot toluene for 2,7- and hot benzene for 2,6-); NMR;
参考文献
Ozawa, Ryota; Yoza, Kenji; Kobayashi, Kenji
Chemistry Letters, 2011 , vol. 40, # 9 p. 941 - 943
反应条件
triethylamine; [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in toluene
参考文献
Canon Kabushiki Kaisha
Patent: US8148543 B2, 2012 ;
Location in patent: Page/Page column 7 ;
