反应条件
1.1: lithium diisopropylamide / tetrahydrofuran; hexane / 0.08 h / -78 °C
1.2: 100 percent / tetrahydrofuran; hexane / -78 - 20 °C
2.1: chiral 4-(pyrrolidino)pyridine-derived Fe(II) complex / hexafluorobenzene / 72 h / 20 °C
3.1: diethyl ether / 12 h / 0 °C
4.1: 0.110 g / [Ph(CF3)2CO]SPh2 / CH2Cl2 / 12 h / 20 °C
5.1: 99 percent / H2 / Pd/C / ethanol / 12 h / 20 °C
6.1: oxalic acid dihydrate / acetone; H2O / 2.5 h / 80 °C
7.1: 0.114 g / NaBH(OAc)3 / 1,2-dichloro-ethane / 12 h / 20 °C
View Scheme
参考文献
Mermerian, Ara H.; Fu, Gregory C.
Angewandte Chemie - International Edition, 2005 , vol. 44, # 6 p. 949 - 952
