5-降冰片烯-2,3-二甲醇合成路线 （共 46 条）
反应条件
in pyridine
Ambient temperature;
参考文献
Fringuelli, Francesco; Piermatti, Oriana; Pizzo, Ferdinando; Scappini, Anna Maria
Gazzetta Chimica Italiana, 1995 , vol. 125, # 4 p. 195 - 200
反应条件
copper trifluoromethanesulfonate in dichloromethane
T=20°C; 24 h;
参考文献
Maas; Mueller
Advanced Synthesis and Catalysis, 1998 , vol. 340, # 4 p. 315 - 322
反应条件
copper trifluoromethanesulfonate in dichloromethane
T=20°C; 24 h; var. of catalyst, solvent, temp., ratio; Product distributionMechanism;
参考文献
Maas; Mueller
Advanced Synthesis and Catalysis, 1998 , vol. 340, # 4 p. 315 - 322
反应条件
1: 42 percent / pyridinium p-toluenesulfonate / benzene / 1 h / Heating
2: KOH
View Scheme
参考文献
Kawashima; Sato; Hatada; Goto; Nakashima; Hatay ama; Shibuya
Chemical and Pharmaceutical Bulletin, 1990 , vol. 38, # 2 p. 393 - 399
参考文献
Gardner,T.S. et al.
Journal of Organic Chemistry, 1961 , vol. 26, p. 1514 - 1518
反应条件
bis-triphenylphosphine-palladium(II) chloride; sodium carbonate; triphenylphosphine in ethylene glycol dimethyl ether; water
T=65°C; Suzuki-Miyaura coupling; 18 h; Inert atmosphere;
参考文献
Thiemann, Thies; Tanaka, Yasuko; Iniesta, Jesus
Molecules, 2009 , vol. 14, # 3 p. 1013 - 1031
反应条件
bis-triphenylphosphine-palladium(II) chloride; sodium carbonate; triphenylphosphine in ethylene glycol dimethyl ether; water
T=65°C; Suzuki-Miyaura coupling; 18 h; Inert atmosphere;
参考文献
Thiemann, Thies; Tanaka, Yasuko; Iniesta, Jesus
Molecules, 2009 , vol. 14, # 3 p. 1013 - 1031
反应条件
1: phosphorus (V)-chloride; benzene / anschliessend mit Zinn(IV)-chlorid behandeln
2: acetic acid; amalgamated zinc; aqueous hydrochloric acid
3: sulfur / 250 °C
View Scheme
参考文献
Horton
Journal of Organic Chemistry, 1949 , vol. 14, p. 761,768
反应条件
potassium permanganate; acetone
参考文献
Wiesner et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 675,682
参考文献
Richards et al.
Journal of the Chemical Society, 1948 , p. 1610
