2-乙炔基-1-甲基-1H-吲哚合成路线 （共 6 条）
反应条件
potassium tert-butylate in methanol
T=100°C; 0.5 h;
参考文献
Baxendale, Ian R.; Ley, Steven V.; Mansfield, Andrew C.; Smith, Christopher D.
Angewandte Chemie, International Edition, 2009 , vol. 48, p. 4017 - 4021
Angewandte Chemie, 2009 , vol. 121, p. 4077 - 4081
反应条件
potassium hydroxide
T=120 - 130°C; P=1.5 Torr;
参考文献
Shvartsberg, M. S.; Vasilevskii, S. F.; Prikhod'ko, T. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 11 p. 2226 - 2229
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 11 p. 2524 - 2527
反应条件
1: 68 percent / BuLi, I2
2: 82.5 percent / (Ph3P)2PdCl2, CuI / triethylamine / 17.5 h / 45 °C
3: 90 percent / KOH / 120 - 130 °C / 1.5 Torr
View Scheme
参考文献
Shvartsberg, M. S.; Vasilevskii, S. F.; Prikhod'ko, T. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 11 p. 2226 - 2229
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 11 p. 2524 - 2527
反应条件
1: 82.5 percent / (Ph3P)2PdCl2, CuI / triethylamine / 17.5 h / 45 °C
2: 90 percent / KOH / 120 - 130 °C / 1.5 Torr
View Scheme
参考文献
Shvartsberg, M. S.; Vasilevskii, S. F.; Prikhod'ko, T. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 11 p. 2226 - 2229
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 11 p. 2524 - 2527
反应条件
1: 90 percent / acetic acid, piperidine / benzene / 24 h / 20 °C
2: 5.7 percent / 600 °C / 0 - 0.01 Torr
View Scheme
参考文献
Benzies, David W. M.; Fresneda, Pilar Martinez; Jones, R. Alan; McNab, Hamish
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1651 - 1654
反应条件
T=600°C; P=0.001 - 0.01 Torr;
参考文献
Benzies, David W. M.; Fresneda, Pilar Martinez; Jones, R. Alan; McNab, Hamish
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1651 - 1654
